Two new highly oxidized humulane sesquiterpenes from the basidiomycete Lactarius mitissimus

CORC > 昆明植物研究所 > 中国科学院昆明植物研究所 > 植物化学与西部植物资源持续利用国家重点实验室

	Two new highly oxidized humulane sesquiterpenes from the basidiomycete Lactarius mitissimus
	Luo, Du-Qiang ; Gao, Yuan ; Yang, Xiao-Long ; Tang, Jian-Guo ; Zhao, Li-Yan ; Liu, Ji-Kai
刊名	HELVETICA CHIMICA ACTA
	2007
卷号	90 期号:6 页码:1112-1116
关键词	Zingiber-aromaticum Zerumbone Metabolites
ISSN号	0018-019X
文献子类	Article
英文摘要	Two new highly oxidized humulane sesquiterpenes, mitissimols F (1) and G (2), were isolated from the fruiting bodies of Lactarius mitissimus. Their structures were elucidated by using extensive spectroscopic techniques including 1D- and 2D-NMR experiments. The absolute configuration of mitissimol F (1) was determined by H-1-NMR resolution of its diastereoisomeric alpha-methoxy-alpha-(trifluoromethyl)benzeneacetates (MTPA). It was shown to be (1S,3E,6S,8R,9R,10S,11R)-8,9:10,11-diepoxy-1,6-dihydroxyhumul-3-en-5-one (=(1S,2R,4R,6S,8E,11S,12R)-6,11-dihydroxy-1,6,10,10-tetramethyl-3,13-dioxatricyclo[10.1.0.0(2.4)]tridec-8-en-7-one).
学科主题	Chemistry ; Multidisciplinary
WOS关键词	ZINGIBER-AROMATICUM ; ZERUMBONE ; METABOLITES
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000247690600006
公开日期	2011-11-24
内容类型	期刊论文
源URL	[http://ir.kib.ac.cn:8080/handle/151853/2041]
专题	昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室
作者单位	1.Hebei Univ, Coll Life Sci, Baoding 071002, Peoples R China 2.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources W China, Kunming Inst Bot, Kunming 650204, Peoples R China
推荐引用方式 GB/T 7714	Luo, Du-Qiang,Gao, Yuan,Yang, Xiao-Long,et al. Two new highly oxidized humulane sesquiterpenes from the basidiomycete Lactarius mitissimus[J]. HELVETICA CHIMICA ACTA,2007,90(6):1112-1116.
APA	Luo, Du-Qiang,Gao, Yuan,Yang, Xiao-Long,Tang, Jian-Guo,Zhao, Li-Yan,&Liu, Ji-Kai.(2007).Two new highly oxidized humulane sesquiterpenes from the basidiomycete Lactarius mitissimus.HELVETICA CHIMICA ACTA,90(6),1112-1116.
MLA	Luo, Du-Qiang,et al."Two new highly oxidized humulane sesquiterpenes from the basidiomycete Lactarius mitissimus".HELVETICA CHIMICA ACTA 90.6(2007):1112-1116.