Isopalhinine A, a Unique Pentacyclic Lycopodium Alkaloid from Palhinhaea cernua

CORC > 昆明植物研究所 > 中国科学院昆明植物研究所 > 植物化学与西部植物资源持续利用国家重点实验室

	Isopalhinine A, a Unique Pentacyclic Lycopodium Alkaloid from Palhinhaea cernua
	Dong, Liao-Bin 1,2; Gao, Xiu 1,2; Liu, Fei1,2 ; He, Juan 1; Wu, Xing-De 1; Li, Yan1 ; Zhao, Qin-Shi1
刊名	ORGANIC LETTERS
	2013-07-19
卷号	15 期号:14 页码:3570-3573
关键词	Unprecedented Skeleton A-c Japonicum Palhinine
ISSN号	1523-7060
通讯作者	Zhao, QS (reprint author), Chinese Acad Sci, State Key Lab Phytochem & Plant Resources West Ch, Kunming Inst Bot, Kunming 650201, Peoples R China. ; qinshizhao@mail.kib.ac.cn
文献子类	Article
英文摘要	A new pentacyclic (5/6/6/6/7) Lycopodium alkaloid named isopalhinine A (1), which possesses a sterically congested architecture built with a tricyclo[4.3.1.0(3,7)]decane (isotwistane) moiety and a 1-azabicyclo[4.3.1]decane moiety, and palhinines B (2) and C (3) were isolated from Palhinhaea cernua. The structure and absolute configuration of 1 were elucidated by a combination of NMR spectra, optical rotation calculation, and X-ray diffraction experiment. A possible biogenetic pathway was also proposed.
学科主题	Chemistry, Organic
WOS关键词	UNPRECEDENTED SKELETON ; A-C ; JAPONICUM ; PALHININE
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000322210600022
资助机构	National Natural Science Foundation [U0932602, 90813004]; National Basic Research Program (973 Program) of China [2011CB915503, 2009CB522303]
公开日期	2013-10-16
内容类型	期刊论文
源URL	[http://ir.kib.ac.cn:8080/handle/151853/16735]
专题	昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室
作者单位	1.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources West Ch, Kunming Inst Bot, Kunming 650201, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Dong, Liao-Bin,Gao, Xiu,Liu, Fei,et al. Isopalhinine A, a Unique Pentacyclic Lycopodium Alkaloid from Palhinhaea cernua[J]. ORGANIC LETTERS,2013,15(14):3570-3573.
APA	Dong, Liao-Bin.,Gao, Xiu.,Liu, Fei.,He, Juan.,Wu, Xing-De.,...&Zhao, Qin-Shi.(2013).Isopalhinine A, a Unique Pentacyclic Lycopodium Alkaloid from Palhinhaea cernua.ORGANIC LETTERS,15(14),3570-3573.
MLA	Dong, Liao-Bin,et al."Isopalhinine A, a Unique Pentacyclic Lycopodium Alkaloid from Palhinhaea cernua".ORGANIC LETTERS 15.14(2013):3570-3573.