The mechanism for the transition from vesicles to punctured lamellae and faceted vesicles in cationic and anionic fluorinated surfactant mixture

doi:http://dx.doi.org/10.1016/j.colsurfa.2016.03.063

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	The mechanism for the transition from vesicles to punctured lamellae and faceted vesicles in cationic and anionic fluorinated surfactant mixture
	Hao, JC; Shen, YW; Lin, HT; Jiang, LH; Ou-Yang, ZC; Liu, ZH; Gao, XH; Gao, XH (reprint author), Shandong Acad Agr Sci, Inst Agr Resources & Environm, Jinan 250100, Peoples R China.
刊名	COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
	2016
卷号	500 页码:40-44
关键词	Cat-anionic Fluorinated Surfactant Faceted Vesicle Punctured Lamellae Surface Charge Self-assembly
DOI	http://dx.doi.org/10.1016/j.colsurfa.2016.03.063
英文摘要	A mixture of cationic and anionic fluorinated surfactants can form faceted vesicles and punctured lamellar phase when there is excess surface charge, in which both cationic and anionic fluorinated surfactants are stiff in the membrane as phospholipids in the frozen "crystalline" or "gel" phase. Here, a model was established to demonstrate the mechanism of the formation and transition of the aggregates with different morphologies. With excess cationic surface charge, the gel-like faceted vesicles and punctured lamellae can transform into smooth-shaped vesicles at high temperature. The freeze-fracture transmission electron microscope (FF-TEM) and X-ray diffraction (XRD) were used to identify the segregation and phase sequence of semi-fluorinated cationic and anionic surfactant membranes with different excess surface charge. (C) 2016 Elsevier B.V. All rights reserved.
学科主题	Chemistry
语种	英语
内容类型	期刊论文
源URL	[http://ir.itp.ac.cn/handle/311006/21598]
专题	理论物理研究所_理论物理所1978-2010年知识产出
通讯作者	Liu, ZH; Gao, XH (reprint author), Shandong Acad Agr Sci, Inst Agr Resources & Environm, Jinan 250100, Peoples R China.
推荐引用方式 GB/T 7714	Hao, JC,Shen, YW,Lin, HT,et al. The mechanism for the transition from vesicles to punctured lamellae and faceted vesicles in cationic and anionic fluorinated surfactant mixture[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2016,500:40-44.
APA	Hao, JC.,Shen, YW.,Lin, HT.,Jiang, LH.,Ou-Yang, ZC.,...&Gao, XH .(2016).The mechanism for the transition from vesicles to punctured lamellae and faceted vesicles in cationic and anionic fluorinated surfactant mixture.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,500,40-44.
MLA	Hao, JC,et al."The mechanism for the transition from vesicles to punctured lamellae and faceted vesicles in cationic and anionic fluorinated surfactant mixture".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 500(2016):40-44.