Graphene oxide reinforced poly(vinyl alcohol) composite fibers via template-oriented crystallization
Zhang, Shengchang1; Liu, Pengqing1; Jia, Erpeng1; Zhao, Xiangsen1; Xu, Jianjun1; Li, Chaolong2
刊名JOURNAL OF POLYMER RESEARCH
2016-09-23
卷号23期号:10页码:14
关键词GO/PVA composite fibers Enhancement Crystallization degree Orientation degree
ISSN号1022-9760
DOI10.1007/s10965-016-1109-z
通讯作者Liu, PQ ; Xu, JJ (reprint author), Sichuan Univ, Coll Polymer Sci & Engn, State Key Lab Polymer Mat & Engn, Chengdu 610065, Peoples R China.
英文摘要Here, a high breaking strength and high initial modulus fibers comprised of polyvinyl alcohol (PVA) and graphene oxide (GO) were fabricated via simple method of solution blending and wet-spinning. The structure and properties of these fibers were studied in details using two-dimensional X-ray diffractions, differential scanning calorimetry, one-dimensional X-ray diffractions, scanning electron microscopy, transmission electron microscopy, dynamic mechanical analysis and tensile test. Compared with pure PVA fiber, a 43 % improvement of breaking strength and an 81 % improvement of initial modulus were achieved by addition of 0.1 wt% of GO, and the results indicated that crystallization and orientation of GO/PVA composite fibers were both increased. GO could not only promote PVA chains ordered arrangement for increasing crystallization, but also act as a template for polymer amorphous orientation via the interactions between PVA and GO in the process of hot drawing and heat setting, which were responsible for the significant improvement in the mechanical properties of GO/PVA composite fibers.
资助项目National Natural Science Foundation of China[51273116] ; Science & Technology Support Program of Sichuan Province[2016GZ0376]
WOS研究方向Polymer Science
语种英语
出版者SPRINGER
WOS记录号WOS:000384575900001
内容类型期刊论文
源URL[http://119.78.100.138/handle/2HOD01W0/2862]  
专题微纳制造与系统集成研究中心
通讯作者Liu, Pengqing; Xu, Jianjun
作者单位1.Sichuan Univ, Coll Polymer Sci & Engn, State Key Lab Polymer Mat & Engn, Chengdu 610065, Peoples R China
2.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing 400714, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Shengchang,Liu, Pengqing,Jia, Erpeng,et al. Graphene oxide reinforced poly(vinyl alcohol) composite fibers via template-oriented crystallization[J]. JOURNAL OF POLYMER RESEARCH,2016,23(10):14.
APA Zhang, Shengchang,Liu, Pengqing,Jia, Erpeng,Zhao, Xiangsen,Xu, Jianjun,&Li, Chaolong.(2016).Graphene oxide reinforced poly(vinyl alcohol) composite fibers via template-oriented crystallization.JOURNAL OF POLYMER RESEARCH,23(10),14.
MLA Zhang, Shengchang,et al."Graphene oxide reinforced poly(vinyl alcohol) composite fibers via template-oriented crystallization".JOURNAL OF POLYMER RESEARCH 23.10(2016):14.
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