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	The influence of triethylamine on the hydrodechlorination reactivity of chlorophenols over Raney Ni catalyst
	Ma, Xuanxuan1,2; Zhou, Shiwei1; Yang, Cuiyun1; Liu, Sujing1; Bi, Xiaoli1; Xia, Chuanhai1
刊名	CATALYSIS COMMUNICATIONS
	2010-12-15
卷号	12期号:4页码:282-285
关键词	Hydrodechlorination (Hdcl) Triethylamine (Et3n) Raney Ni Chlorophenol (Cp) Catalytic Reactivity/selectivity
通讯作者	Xia, C. (chxia@yic.ac.cn)
产权排序	(1) Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences;(2) Graduate School, Chinese Academy of Sciences;
文献子类	Article
英文摘要	The hydrodechlorination (HDCl) of 2,4-dichlorophenol (2,4-DCP), 2-chlorophenol (2-CP) and 4-chlorophenol (4-CP) over Raney Ni in liquid phase with triethylamine (Et3N) under mild conditions was studied. The results showed that Et3N together with solvents significantly affected the HDCl reactivity or selectivity, in which ortho-positioned Cl of chlorophenols (CPs) was easier to be dechlorinated in methanol (MeOH) and ethanol (EtOH), whereas para-positioned Cl was preferentially dechlorinated in water. Different species and action mechanisms of Et3N in water and organic solvents possibly affected the HDCl reactivity or selectivity of CPs over Raney Ni.; The hydrodechlorination (HDCl) of 2 4-dichlorophenol (2 4-DCP) 2-chlorophenol (2-CP) and 4-chlorophenol (4-CP) over Raney Ni in liquid phase with triethylamine (Et3N) under mild conditions was studied The results showed that Et3N together with solvents significantly affected the HDCl reactivity or selectivity in which ortho-positioned Cl of chlorophenols (CPs) was easier to be dechlorinated in methanol (MeOH) and ethanol (EtOH) whereas para-positioned Cl was preferentially dechlorinated in water Different species and action mechanisms of Et3N in water and organic solvents possibly affected the HDCl reactivity or selectivity of CPs over Raney Ni (C) 2010 Elsevier BV All rights reserved
WOS关键词	LIQUID-PHASE HYDRODECHLORINATION ; MILD CONDITIONS ; AQUEOUS-SOLUTIONS ; PD/C ; 2,4-DICHLOROPHENOL ; PD/AL2O3 ; HYDROGENATION ; TEMPERATURE ; HYDROGENOLYSIS ; DEACTIVATION
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000285438300009
公开日期	2011-07-14
内容类型	期刊论文
源URL	[http://ir.yic.ac.cn/handle/133337/3672]
专题	烟台海岸带研究所_海岸带生物学与生物资源利用所重点实验室
作者单位	1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Ma, Xuanxuan,Zhou, Shiwei,Yang, Cuiyun,et al. The influence of triethylamine on the hydrodechlorination reactivity of chlorophenols over Raney Ni catalyst[J]. CATALYSIS COMMUNICATIONS,2010,12(4):282-285.
APA	Ma, Xuanxuan,Zhou, Shiwei,Yang, Cuiyun,Liu, Sujing,Bi, Xiaoli,&Xia, Chuanhai.(2010).The influence of triethylamine on the hydrodechlorination reactivity of chlorophenols over Raney Ni catalyst.CATALYSIS COMMUNICATIONS,12(4),282-285.
MLA	Ma, Xuanxuan,et al."The influence of triethylamine on the hydrodechlorination reactivity of chlorophenols over Raney Ni catalyst".CATALYSIS COMMUNICATIONS 12.4(2010):282-285.

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