Efficient Synthesis of Furfuryl Alcohol from H-2-Hydrogenation/Transfer Hydrogenation of Furfural Using Sulfonate Group Modified Cu Catalyst

doi:10.1021/acssuschemeng.6b02343

CORC > 合肥物质科学研究院 > 中国科学院合肥物质科学研究院 > 中科院固体物理研究所

	Efficient Synthesis of Furfuryl Alcohol from H-2-Hydrogenation/Transfer Hydrogenation of Furfural Using Sulfonate Group Modified Cu Catalyst
	Gong, Wanbing 1,2; Chen, Chun 1; Zhang, Yong1,2 ; Zhou, Hongjian 1; Wang, Huimin 1; Zhang, Haimin 1; Zhang, Yunxia 1; Wang, Guozhong 1; Zhao, Huijun 1,3
刊名	ACS SUSTAINABLE CHEMISTRY & ENGINEERING
	2017-03-01
卷号	5 期号:3 页码:2172-2180
关键词	Furfural Furfuryl Alcohol Cu Catalyst Sulfonate Group Liquid Phase Hydrogenation
DOI	10.1021/acssuschemeng.6b02343
文献子类	Article
英文摘要	A copper-based catalyst, which was supported by sulfonate group (-SO3H) grafted active carbon (AC), was prepared and activated simultaneously by liquid phase chemical reduction method. The modified copper catalyst, Cu/AC-SO3H, displayed an enhanced catalytic performance for selective hydrogenation of furfural (FAL) to furfuryl alcohol (FOL) in liquid phase, in which almost 100% FOL yield was obtained at 378 K and 0.4 MPa of hydrogen pressure after 120 min reaction. The effect of SO3H was evaluated and illustrated by the combination of reaction performance and physicochemical characterizations, such as X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and X-ray photoelectron spectrometer (XPS) measurements. Through grafting sulfonate group on the support, better dispersion of nanoparticles, higher reduction degree stronger adsorption of FAL can be attained to contribute high hydrogenation performance. In addition, the effects conditions (such as reaction temperature, H-2 pressure, reaction time, solvent, and catalyst to FAL mass ratio) were evaluated intensively. Also, the Cu/AC SO3H catalyst showed an excellent catalytic performance for transfer hydrogenation of FAL, in which 2-propanol was utilized as the solvent and hydrogen donor concurrently. Cycling test proved the prepared catalyst Could be recycled and reused for several times without noticeably reduced catalytic activity of hydrogenation.
WOS关键词	PHASE HYDROGENATION ; SELECTIVE HYDROGENATION ; BIFUNCTIONAL CATALYST ; BIODIESEL PRODUCTION ; FUEL ADDITIVES ; ACID CATALYST ; CONVERSION ; BIOMASS ; CARBON ; LIQUID
WOS研究方向	Chemistry ; Engineering
语种	英语
WOS记录号	WOS:000395846900019
资助机构	Natural Science Foundation of China(51502297 ; Natural Science Foundation of China(51502297 ; Natural Science Foundation of China(51502297 ; Natural Science Foundation of China(51502297 ; Instrument Developing Project of the Chinese Academy of Sciences(yz201421) ; Instrument Developing Project of the Chinese Academy of Sciences(yz201421) ; Instrument Developing Project of the Chinese Academy of Sciences(yz201421) ; Instrument Developing Project of the Chinese Academy of Sciences(yz201421) ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; Potential Program (Hefei Science Center, CAS)(2015HSC-UP006) ; Potential Program (Hefei Science Center, CAS)(2015HSC-UP006) ; Potential Program (Hefei Science Center, CAS)(2015HSC-UP006) ; Potential Program (Hefei Science Center, CAS)(2015HSC-UP006) ; 51372248 ; 51372248 ; 51372248 ; 51372248 ; 51432009) ; 51432009) ; 51432009) ; 51432009) ; Natural Science Foundation of China(51502297 ; Natural Science Foundation of China(51502297 ; Natural Science Foundation of China(51502297 ; Natural Science Foundation of China(51502297 ; Instrument Developing Project of the Chinese Academy of Sciences(yz201421) ; Instrument Developing Project of the Chinese Academy of Sciences(yz201421) ; Instrument Developing Project of the Chinese Academy of Sciences(yz201421) ; Instrument Developing Project of the Chinese Academy of Sciences(yz201421) ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; Potential Program (Hefei Science Center, CAS)(2015HSC-UP006) ; Potential Program (Hefei Science Center, CAS)(2015HSC-UP006) ; Potential Program (Hefei Science Center, CAS)(2015HSC-UP006) ; Potential Program (Hefei Science Center, CAS)(2015HSC-UP006) ; 51372248 ; 51372248 ; 51372248 ; 51372248 ; 51432009) ; 51432009) ; 51432009) ; 51432009)
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/32932]
专题	合肥物质科学研究院_中科院固体物理研究所
作者单位	1.Chinese Acad Sci, Inst Solid State Phys, Ctr Environm & Energy Nanomat, Key Lab Mat Phys,Anhui Key Lab Nanomat & Nanotech, Hefei 230031, Peoples R China 2.Univ Sci & Technol China, Hefei 230026, Anhui, Peoples R China 3.Griffith Univ, Ctr Clean Environm & Energy, Gold Coast Campus, Southport, Qld 4222, Australia
推荐引用方式 GB/T 7714	Gong, Wanbing,Chen, Chun,Zhang, Yong,et al. Efficient Synthesis of Furfuryl Alcohol from H-2-Hydrogenation/Transfer Hydrogenation of Furfural Using Sulfonate Group Modified Cu Catalyst[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2017,5(3):2172-2180.
APA	Gong, Wanbing.,Chen, Chun.,Zhang, Yong.,Zhou, Hongjian.,Wang, Huimin.,...&Zhao, Huijun.(2017).Efficient Synthesis of Furfuryl Alcohol from H-2-Hydrogenation/Transfer Hydrogenation of Furfural Using Sulfonate Group Modified Cu Catalyst.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,5(3),2172-2180.
MLA	Gong, Wanbing,et al."Efficient Synthesis of Furfuryl Alcohol from H-2-Hydrogenation/Transfer Hydrogenation of Furfural Using Sulfonate Group Modified Cu Catalyst".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 5.3(2017):2172-2180.