Conversion of 5-hydroxymethylfurfural into 5-ethoxymethylfurfural and ethyl levulinate catalyzed by MOF-based heteropolyacid materials

doi:10.1039/c6gc01206j

CORC > 合肥物质科学研究院 > 中国科学院合肥物质科学研究院 > 中科院强磁场科学中心

	Conversion of 5-hydroxymethylfurfural into 5-ethoxymethylfurfural and ethyl levulinate catalyzed by MOF-based heteropolyacid materials
	Wang, Zhenhua 1,2; Chen, Qianwang 1,2,3
刊名	GREEN CHEMISTRY
	2016
卷号	18 期号:21 页码:5884-5889
DOI	10.1039/c6gc01206j
文献子类	Article
英文摘要	Conversion of 5-hydroxymethylfurfural (HMF) into 5-ethoxymethylfurfural (EMF) and ethyl levulinate (EL) is an attractive biomass transformation due to its potential application in the energy and chemical industries. Here, we report on the conversion with MOF-based polyoxometalate [Cu-BTC][ HPM] (NENU-5) as the catalyst. The homogeneous distribution of HPM in the pores of Cu-BTC makes the composite combine the properties of the catalytic activity of HPM and the insolubility, large surface area and hierarchical pores of Cu-BTC. The catalyst demonstrates reusability and catalytic activity with 55% yield of EMF and 11% yield of EL.
WOS关键词	SUPPORTED PHOSPHOTUNGSTIC ACID ; METAL-ORGANIC FRAMEWORKS ; GAMMA-VALEROLACTONE ; LIGNOCELLULOSIC BIOMASS ; K-10 CLAY ; FRUCTOSE ; LIQUID ; CHEMICALS ; CELLULOSE ; BIOFUEL
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000386425000023
资助机构	National Natural Science Foundation (NSFC)(21271163 ; National Natural Science Foundation (NSFC)(21271163 ; National Natural Science Foundation (NSFC)(21271163 ; National Natural Science Foundation (NSFC)(21271163 ; CAS/SAFEA international partnership program for creative research teams ; CAS/SAFEA international partnership program for creative research teams ; CAS/SAFEA international partnership program for creative research teams ; CAS/SAFEA international partnership program for creative research teams ; CAS Hefei Science Center(2016HSC-IU011) ; CAS Hefei Science Center(2016HSC-IU011) ; CAS Hefei Science Center(2016HSC-IU011) ; CAS Hefei Science Center(2016HSC-IU011) ; U1232211) ; U1232211) ; U1232211) ; U1232211) ; National Natural Science Foundation (NSFC)(21271163 ; National Natural Science Foundation (NSFC)(21271163 ; National Natural Science Foundation (NSFC)(21271163 ; National Natural Science Foundation (NSFC)(21271163 ; CAS/SAFEA international partnership program for creative research teams ; CAS/SAFEA international partnership program for creative research teams ; CAS/SAFEA international partnership program for creative research teams ; CAS/SAFEA international partnership program for creative research teams ; CAS Hefei Science Center(2016HSC-IU011) ; CAS Hefei Science Center(2016HSC-IU011) ; CAS Hefei Science Center(2016HSC-IU011) ; CAS Hefei Science Center(2016HSC-IU011) ; U1232211) ; U1232211) ; U1232211) ; U1232211)
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/30149]
专题	合肥物质科学研究院_中科院强磁场科学中心
作者单位	1.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei, Peoples R China 2.Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei, Peoples R China 3.Chinese Acad Sci, Hefei Inst Phys Sci, High Magnet Field Lab, Hefei 230031, Anhui, Peoples R China
推荐引用方式 GB/T 7714	Wang, Zhenhua,Chen, Qianwang. Conversion of 5-hydroxymethylfurfural into 5-ethoxymethylfurfural and ethyl levulinate catalyzed by MOF-based heteropolyacid materials[J]. GREEN CHEMISTRY,2016,18(21):5884-5889.
APA	Wang, Zhenhua,&Chen, Qianwang.(2016).Conversion of 5-hydroxymethylfurfural into 5-ethoxymethylfurfural and ethyl levulinate catalyzed by MOF-based heteropolyacid materials.GREEN CHEMISTRY,18(21),5884-5889.
MLA	Wang, Zhenhua,et al."Conversion of 5-hydroxymethylfurfural into 5-ethoxymethylfurfural and ethyl levulinate catalyzed by MOF-based heteropolyacid materials".GREEN CHEMISTRY 18.21(2016):5884-5889.