Tuning the Thickness of Ba-Containing "Functional" Layer toward High-Performance Ceria-Based Solid Oxide Fuel Cells | |
Gong, Zheng1,2; Sun, Wenping3; Shan, Duo1,2; Wu, Yusen1,2; Liu, Wei1,2,4 | |
刊名 | ACS APPLIED MATERIALS & INTERFACES |
2016-05-04 | |
卷号 | 8期号:17页码:10835-10840 |
关键词 | Doped Ceria Electron-blocking Layer Open Circuit Voltage Solid Oxide Fuel Cells Internal Short Circuit |
DOI | 10.1021/acsami.6b01000 |
文献子类 | Article |
英文摘要 | Developing highly efficient ceria-based solid oxide fuel cells with high power density is still a big concern for commercial applications. In this work, a novel structured Ce0.8Sm0.2O2-delta (SDC)-based fuel cell with a bilayered anode consisting of Ni-SDC and Ni-BaZr0.1Ce0.7Y0.2O3-delta (Ni-BZCY) was designed. In addition to the catalysis function, the Ni-BZCY anode "functional" layer also provides Ba source for generating an electron-blocking layer in situ at the anode/electrolyte interface during sintering. The Ni-BZCY thickness significantly influences the quality of the electron-blocking layer and electrochemical performances of the The cell with a 50 mu m thick Ni-BZCY layer exhibits the best performance in terms of open circuit voltage (OCV) and peak power density (1068 mW cm(-2) at 650 degrees C). The results demonstrate that this cell with an optimal structure has a distinct advantage of delivering high power performance with a high efficiency at reduced temperatures. |
WOS关键词 | ANODE-SUPPORTED SOFC ; COMPOSITE CATHODE ; BILAYER ELECTROLYTE ; SDC ELECTROLYTE ; TEMPERATURE ; FABRICATION ; FILM ; STABILITY ; EFFICIENT ; CIRCUIT |
WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
语种 | 英语 |
WOS记录号 | WOS:000375520700022 |
资助机构 | Ministry of Science and Technology of China(2012CB215403) ; Ministry of Science and Technology of China(2012CB215403) ; Ministry of Science and Technology of China(2012CB215403) ; Ministry of Science and Technology of China(2012CB215403) ; National Science Foundation of China(21506168) ; National Science Foundation of China(21506168) ; National Science Foundation of China(21506168) ; National Science Foundation of China(21506168) ; Ministry of Science and Technology of China(2012CB215403) ; Ministry of Science and Technology of China(2012CB215403) ; Ministry of Science and Technology of China(2012CB215403) ; Ministry of Science and Technology of China(2012CB215403) ; National Science Foundation of China(21506168) ; National Science Foundation of China(21506168) ; National Science Foundation of China(21506168) ; National Science Foundation of China(21506168) |
内容类型 | 期刊论文 |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/22402] |
专题 | 合肥物质科学研究院_中科院固体物理研究所 |
作者单位 | 1.Univ Sci & Technol China, CAS Key Lab Mat Energy Convers, Hefei 230026, Peoples R China 2.Univ Sci & Technol China, Collaborat Innovat Ctr Suzhou Nano Sci & Technol, Hefei 230026, Peoples R China 3.Univ Wollongong, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia 4.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Peoples R China |
推荐引用方式 GB/T 7714 | Gong, Zheng,Sun, Wenping,Shan, Duo,et al. Tuning the Thickness of Ba-Containing "Functional" Layer toward High-Performance Ceria-Based Solid Oxide Fuel Cells[J]. ACS APPLIED MATERIALS & INTERFACES,2016,8(17):10835-10840. |
APA | Gong, Zheng,Sun, Wenping,Shan, Duo,Wu, Yusen,&Liu, Wei.(2016).Tuning the Thickness of Ba-Containing "Functional" Layer toward High-Performance Ceria-Based Solid Oxide Fuel Cells.ACS APPLIED MATERIALS & INTERFACES,8(17),10835-10840. |
MLA | Gong, Zheng,et al."Tuning the Thickness of Ba-Containing "Functional" Layer toward High-Performance Ceria-Based Solid Oxide Fuel Cells".ACS APPLIED MATERIALS & INTERFACES 8.17(2016):10835-10840. |
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