HF-Free Synthesis of Nanoscale Metal-Organic Framework NMIL-100(Fe) as an Efficient Dye Adsorbent

doi:10.1021/acs.suschemeng.6b00434

CORC > 合肥物质科学研究院 > 中国科学院合肥物质科学研究院 > 中科院等离子体物理研究所

	HF-Free Synthesis of Nanoscale Metal-Organic Framework NMIL-100(Fe) as an Efficient Dye Adsorbent
	Duan, Shengxia 1,2; Li, Jiaxing 1,4,5,6; Liu, Xia 1,2; Wang, Yanan 1,2; Zeng, Suyuan 3; Shao, Dadong 1; Hayat, Tasawar 4
刊名	ACS SUSTAINABLE CHEMISTRY & ENGINEERING
	2016-06-01
卷号	4 期号:6 页码:3368-3378
关键词	Hf-free Metal-organic Framework Nmil-100(Fe) Adsorption Dyes
DOI	10.1021/acs.suschemeng.6b00434
文献子类	Article
英文摘要	A hydrofluoric acid (HF)-free solvothermal method was used to synthesize nanoscale metal organic framework NMIL-100(Fe), which exhibited comparable physicochemical properties as those prepared by traditional methods, but with a mild and environmentally benign synthesis condition. XRD, TGA, N-2 adsorption, FT-IR, SEM, and TEM were employed to characterize the as prepared NMIL-100(Fe), which was further applied as an effective adsorbent for dye adsorption, including two cationic dyes, rhodamine 6G (R6G) and rhodamine B (RB), and an anionic reactive red 120 (RR 120) with high adsorption efficiencies and capacities. The adsorption process can be well described by pseudo-second-order kinetic model and Langmuir isotherm model. Hydrogen bonding and electrostatic interaction were revealed for the adsorption of the two cationic dyes and one anionic dye onto NMIL-100(Fe), respectively, as investigated by mechanism studies. Thermodynamic analyses indicate that adsorption processes for cationic and anionic dyes are entropy-driven endothermic and enthalpy-driven exothermic processes, respectively. This environmental-benign synthetic strategy for NMIL-100(Fe), as well as its high adsorption efficiency and capacity, might be used for the fabrication of other nanoscale metal organic frameworks, and the potential applications of NMIL-100(Fe) in real wastewater treatment.
WOS关键词	REACTIVE RED 120 ; MICROPOROUS COORDINATION POLYMERS ; AQUEOUS-SOLUTION ; THERMODYNAMIC BEHAVIORS ; EFFECTIVE REMOVAL ; ACTIVATED CARBON ; GRAPHENE OXIDE ; RHODAMINE 6G ; ADSORPTION ; MIL-100(FE)
WOS研究方向	Chemistry ; Engineering
语种	英语
WOS记录号	WOS:000377425900051
资助机构	National Natural Science Foundation of China(1U1530131 ; National Natural Science Foundation of China(1U1530131 ; National Natural Science Foundation of China(1U1530131 ; National Natural Science Foundation of China(1U1530131 ; National Natural Science Foundation of China(1U1530131 ; National Natural Science Foundation of China(1U1530131 ; National Natural Science Foundation of China(1U1530131 ; National Natural Science Foundation of China(1U1530131 ; National Natural Science Foundation of China(1U1530131 ; National Natural Science Foundation of China(1U1530131 ; National Natural Science Foundation of China(1U1530131 ; National Natural Science Foundation of China(1U1530131 ; National Natural Science Foundation of China(1U1530131 ; National Natural Science Foundation of China(1U1530131 ; National Natural Science Foundation of China(1U1530131 ; National Natural Science Foundation of China(1U1530131 ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; 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special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; special scientific research fund of public welfare profession of China(201509074) ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; Priority Academic Program Development of Jiangsu Higher Education Institutions ; 21272236 ; 21272236 ; 21272236 ; 21272236 ; 21272236 ; 21272236 ; 21272236 ; 21272236 ; 21272236 ; 21272236 ; 21272236 ; 21272236 ; 21272236 ; 21272236 ; 21272236 ; 21272236 ; 21373106) ; 21373106) ; 21373106) ; 21373106) ; 21373106) ; 21373106) ; 21373106) ; 21373106) ; 21373106) ; 21373106) ; 21373106) ; 21373106) ; 21373106) ; 21373106) ; 21373106) ; 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内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn/handle/334002/21411]
专题	合肥物质科学研究院_中科院等离子体物理研究所
作者单位	1.Chinese Acad Sci, Inst Plasma Phys, Key Lab Novel Thin Film Solar Cells, POB 1126, Hefei 230031, Peoples R China 2.Univ Sci & Technol China, Hefei 230026, Peoples R China 3.Liaocheng Univ, Sch Chem & Chem Engn, Liaocheng 252059, Peoples R China 4.King Abdulaziz Univ, Fac Sci, NAAM Res Grp, Jeddah 21589, Saudi Arabia 5.Soochow Univ, Collaborat Innovat Ctr Radiat Med Jiangsu Higher, Suzhou 215123, Peoples R China 6.Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, Suzhou 215123, Peoples R China
推荐引用方式 GB/T 7714	Duan, Shengxia,Li, Jiaxing,Liu, Xia,et al. HF-Free Synthesis of Nanoscale Metal-Organic Framework NMIL-100(Fe) as an Efficient Dye Adsorbent[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2016,4(6):3368-3378.
APA	Duan, Shengxia.,Li, Jiaxing.,Liu, Xia.,Wang, Yanan.,Zeng, Suyuan.,...&Hayat, Tasawar.(2016).HF-Free Synthesis of Nanoscale Metal-Organic Framework NMIL-100(Fe) as an Efficient Dye Adsorbent.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,4(6),3368-3378.
MLA	Duan, Shengxia,et al."HF-Free Synthesis of Nanoscale Metal-Organic Framework NMIL-100(Fe) as an Efficient Dye Adsorbent".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 4.6(2016):3368-3378.