Selectively Converting Biomass to Jet Fuel in Large-scale Apparatus

	Selectively Converting Biomass to Jet Fuel in Large-scale Apparatus
	Fan, Ronggang 3; Yoneyama, Yoshiharu 1; Yang, Guohui 1; Tsubaki, Noritatsu 1; Li, Jie 1; Sun, Jian 1,2
刊名	CHEMCATCHEM
	2017-07-24
卷号	9 期号:14 页码:2668-2674
关键词	Anderson-Schulz-Flory distribution biomass Fischer-Tropsch synthesis gasification jet fuel
英文摘要	Jet fuel is not easy to synthesize by the biomass-to-liquid (BTL) process owing to the limitation of the Anderson-Schulz-Flory (ASF) hydrocarbon distribution law in Fischer-Tropsch synthesis (FTS) with biomass-derived syngas (CO+H2). Here, we realized an anti-ASF distribution to selectively produce jet fuel from biomass on a large scale by addition of small amounts of 1-olefin, a FTS product, into syngas, enhancing jet fuel selectivity in hydrocarbons up to 64% and that in oil product to as high as 91%. The Co/SiO2 catalyst (300 g) was loaded into a flow-type three-phase reactor and 120h continuous operation was conducted by using the real-time on-line biomass- derived syngas from an entrained bed gasifier of biomass (240 kg day(-1)) of Mitsubishi Heavy Industries, Ltd. The production rate of liquid oil reached 720 g kg(cat)(-1)h(-1). The structure of the fresh and used catalyst was characterized in detail, accompanied with lab-scale data on reaction performance and catalyst properties. The stable technology process from biomass gasification to FTS, stable catalyst structure, and novel design of 1-olefin addition are the key to success in selectively converting biomass to jet fuel on a large scale.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Physical
研究领域[WOS]	Chemistry
关键词[WOS]	FISCHER-TROPSCH SYNTHESIS ; BIMODAL CATALYST ; COBALT ; CONVERSION ; NANOPARTICLES ; DEACTIVATION ; HYDROCARBONS ; PRODUCT
收录类别	SCI
语种	英语
WOS记录号	WOS:000406243100010
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/151904]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Univ Toyama, Dept Appl Chem, Sch Engn, Gofuku 3190, Toyama 9308555, Japan 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy DNL, Dalian 116023, Peoples R China 3.Shinka Co Ltd, Gofuku 3383-4, Toyama, Japan
推荐引用方式 GB/T 7714	Fan, Ronggang,Yoneyama, Yoshiharu,Yang, Guohui,et al. Selectively Converting Biomass to Jet Fuel in Large-scale Apparatus[J]. CHEMCATCHEM,2017,9(14):2668-2674.
APA	Fan, Ronggang,Yoneyama, Yoshiharu,Yang, Guohui,Tsubaki, Noritatsu,Li, Jie,&Sun, Jian.(2017).Selectively Converting Biomass to Jet Fuel in Large-scale Apparatus.CHEMCATCHEM,9(14),2668-2674.
MLA	Fan, Ronggang,et al."Selectively Converting Biomass to Jet Fuel in Large-scale Apparatus".CHEMCATCHEM 9.14(2017):2668-2674.