Fischer-Tropsch synthesis on impregnated cobalt-based catalysts: New insights into the effect of impregnation solutions and pH value | |
Sun, Jian3; Yamane, Noriyuki5; Yang, Ruiqin2; Gao, Xinhua2; Zhang, Peipei2; Ai, Peipei2; Xing, Chuang1; Tsubaki, Noritatsu1,2; Reubroycharoen, Prasert4 | |
刊名 | JOURNAL OF ENERGY CHEMISTRY |
2016-11-01 | |
卷号 | 25期号:6页码:994-1000 |
关键词 | Fischer-Tropsch synthesis Co catalyst pH value Impregnation solution |
英文摘要 | The Co-based catalysts were prepared with different cobalt acetate solutions. Effects of pH value were studied deeply on Fischer-Tropsch synthesis (FTS) through a semi-batch reactor. Among all impregnation solutions (water, butanol, amyl alcohol, acetic acid, nitric acid and ammonium nitrate), the catalyst prepared by NH4 NO3 solution showed the highest catalytic activity due to its small particle size and high reduction degree. However, the catalyst with the smallest particle size derived from water as impregnation solution exhibited low activity as well as high methane selectivity since it was difficult to be reduced and inactive in FTS. According to FT-IR spectra results, the low intensity of absorbed CO on the catalyst prepared from water solution resulted in low FTS activity. Whereas, the high activity of catalysts prepared from NH4 NO3 solution could be explained by the high intensity of absorbed CO on the catalysts. The cobalt species on the catalysts prepared under lower pH conditions exhibited smaller particle size distribution as well as lower CO conversion than those prepared at higher pH value. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B. V. and Science Press. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
类目[WOS] | Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical |
研究领域[WOS] | Chemistry ; Energy & Fuels ; Engineering |
关键词[WOS] | CO-BASED CATALYSTS ; CO/SIO2 CATALYSTS ; SILICA ; NANOPARTICLES ; SUPPORT ; ALUMINA ; DESIGN ; SIZE |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000390132200011 |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/151822] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Zhejiang Univ Sci & Technol, Sch Biol & Chem Engn, Hangzhou 310023, Zhejiang, Peoples R China 2.Toyama Univ, Dept Appl Chem, Grad Sch Engn, Toyama 9308555, Japan 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy DNL, Dalian 116023, Liaoning, Peoples R China 4.Chulalongkorn Univ, Fac Sci, Dept Chem Technol, Bangkok 10330, Thailand 5.Nippon Steel & Sumitomo Met Corp, Adv Technol Res Labs 20 1, Futtsu 2938511, Japan |
推荐引用方式 GB/T 7714 | Sun, Jian,Yamane, Noriyuki,Yang, Ruiqin,et al. Fischer-Tropsch synthesis on impregnated cobalt-based catalysts: New insights into the effect of impregnation solutions and pH value[J]. JOURNAL OF ENERGY CHEMISTRY,2016,25(6):994-1000. |
APA | Sun, Jian.,Yamane, Noriyuki.,Yang, Ruiqin.,Gao, Xinhua.,Zhang, Peipei.,...&Reubroycharoen, Prasert.(2016).Fischer-Tropsch synthesis on impregnated cobalt-based catalysts: New insights into the effect of impregnation solutions and pH value.JOURNAL OF ENERGY CHEMISTRY,25(6),994-1000. |
MLA | Sun, Jian,et al."Fischer-Tropsch synthesis on impregnated cobalt-based catalysts: New insights into the effect of impregnation solutions and pH value".JOURNAL OF ENERGY CHEMISTRY 25.6(2016):994-1000. |
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