120 mm single-crystalline perovskite and wafers: towards viable applications

	120 mm single-crystalline perovskite and wafers: towards viable applications
	Liu, Shengzhong (Frank)1,2,3,4,5,6; Liu, Yucheng 2,3,4,5; Ren, Xiaodong 2,3,4,5; Zhang, Jing 1,6; Yang, Zhou 2,3,4,5; Yang, Dong 2,3,4,5; Yu, Fengyang 2,3,4,5; Sun, Jiankun 2,3,4,5; Zhao, Changming 2,3,4,5; Yao, Zhun 2,3,4,5
刊名	SCIENCE CHINA-CHEMISTRY
	2017-10-01
卷号	60 期号:10 页码:1367-1376
关键词	single-crystal growth perovskite wafer IC devices photodetector array
英文摘要	As the large single-crystalline silicon wafers have revolutionized many industries including electronics and solar cells, it is envisioned that the availability of large single-crystalline perovskite crystals and wafers will revolutionize its broad applications in photovoltaics, optoelectronics, lasers, photodetectors, light emitting diodes (LEDs), etc. Here we report a method to grow large single-crystalline perovskites including single-halide crystals: CH3NH3PbX3 (X=I, Br, Cl), and dual-halide ones: CH3NH3Pb(Cl (x) Br1-x )(3) and CH3NH3Pb(Br (x) I1-x )(3), with the largest crystal being 120 mm in length. Meanwhile, we have advanced a process to slice the large perovskite crystals into thin wafers. It is found that the wafers exhibit remarkable features: (1) its trap-state density is a million times smaller than that in the microcrystalline perovskite thin films (MPTF); (2) its carrier mobility is 410 times higher than its most popular organic counterpart P3HT; (3) its optical absorption is expanded to as high as 910 nm comparing to 797 nm for the MPTF; (4) while MPTF decomposes at 150 A degrees C, the wafer is stable at high temperature up to 270 A degrees C; (5) when exposed to high humidity (75% RH), MPTF decomposes in 5 h while the wafer shows no change for overnight; (6) its photocurrent response is 250 times higher than its MPTF counterpart. A few electronic devices have been fabricated using the crystalline wafers. Among them, the Hall test gives low carrier concentration with high mobility. The trap-state density is measured much lower than common semiconductors. Moreover, the large SC-wafer is found particularly useful for mass production of integrated circuits. By adjusting the halide composition, both the optical absorption and the light emission can be fine-tuned across the entire visible spectrum from 400 nm to 800 nm. It is envisioned that a range of visible lasers and LEDs may be developed using the dual-halide perovskites. With fewer trap states, high mobility, broader absorption, and humidity resistance, it is expected that solar cells with high stable efficiency maybe attainable using the crystalline wafers.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	HYBRID PEROVSKITE ; SOLAR-CELLS ; STATE ; TEMPERATURE ; CH3NH3PBI3 ; EFFICIENCY ; PHOTODETECTORS ; PERFORMANCE ; DIFFUSION ; DENSITY
收录类别	SCI
语种	英语
WOS记录号	WOS:000415714400016
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/149696]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Shaanxi Normal Univ, Natl Minist Educ, Key Lab Appl Surface & Colloid Chem, Xian 710119, Shaanxi, Peoples R China 3.Shaanxi Normal Univ, Shaanxi Key Lab Adv Energy Devices, Xian 710119, Shaanxi, Peoples R China 4.Shaanxi Normal Univ, Shaanxi Engn Lab Adv Energy Technol, Xian 710119, Shaanxi, Peoples R China 5.Shaanxi Normal Univ, Sch Mat Sci & Engn, Xian 710119, Shaanxi, Peoples R China 6.Chinese Acad Sci, iChEM, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 7.Xian LONGI Silicon Mat Corp, Xian 710100, Shaanxi, Peoples R China
推荐引用方式 GB/T 7714	Liu, Shengzhong ,Liu, Yucheng,Ren, Xiaodong,et al. 120 mm single-crystalline perovskite and wafers: towards viable applications[J]. SCIENCE CHINA-CHEMISTRY,2017,60(10):1367-1376.
APA	Liu, Shengzhong .,Liu, Yucheng.,Ren, Xiaodong.,Zhang, Jing.,Yang, Zhou.,...&Fan, Haibo.(2017).120 mm single-crystalline perovskite and wafers: towards viable applications.SCIENCE CHINA-CHEMISTRY,60(10),1367-1376.
MLA	Liu, Shengzhong ,et al."120 mm single-crystalline perovskite and wafers: towards viable applications".SCIENCE CHINA-CHEMISTRY 60.10(2017):1367-1376.