Facile synthesis of spinel LiNi0.5Mn1.5O4 cathode materials using M-2(OH)(2)(C8H4O4)-class metal-organic frameworks | |
Ren, Wenfeng1; Yang, Shifeng1,2; Chen, Jian1 | |
刊名 | IONICS |
2017-11-01 | |
卷号 | 23期号:11页码:2969-2980 |
关键词 | Cathode materials LiNi0.5Mn1.5O4 Metal-organic frameworks PTA |
英文摘要 | Various synthesis methods have been developed to synthesize mixed metal oxide cathode materials, whereas the scale-up production is hindered by issues of complicated processes, high cost, and inhomogeneity of the prepared materials. Herein, a facile, low-cost, and scalable synthesis route using M-2(OH)(2)(C8H4O4)-class metal-organic frameworks (PTA-based MOFs) as precursors has been explored to synthesize LiNi0.5Mn1.5O4 materials with homogeneity and high crystallinity. Bimetallic PTA-based MOFs were first prepared by the reaction of metal acetates and PTA in the aqueous solution at room temperature. After thermal treatment of PTA-based MOFs, bimetal oxides (Ni-Mn-O) with the inherited morphology of porous nanoplates consisting of 20-30-nm nanoparticles were obtained. The LiNi0.5Mn1.5O4 materials prepared by calcination of Ni-Mn-O with lithium salts exhibit excellent rate capability and cycling performance, delivering a specific capacity of 115.9 mAh g(-1) at 20 C and retaining 83.8% after 500 cycles. This work opens a new way for fabrication of PTA-based MOFs and mixed metal oxides as cathode materials for lithium-ion batteries. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Physical ; Electrochemistry ; Physics, Condensed Matter |
研究领域[WOS] | Chemistry ; Electrochemistry ; Physics |
关键词[WOS] | LITHIUM-ION BATTERIES ; LONG-CYCLE-LIFE ; HIGH-POWER ; ELECTROCHEMICAL PERFORMANCES ; SURFACE MODIFICATION ; ELECTRODE MATERIAL ; CAPACITY ; SUPERCAPACITORS ; NANOSTRUCTURES ; LIMN1.5NI0.5O4 |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000414026000003 |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/149675] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Adv Rechargeable Battery Lab, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Ren, Wenfeng,Yang, Shifeng,Chen, Jian. Facile synthesis of spinel LiNi0.5Mn1.5O4 cathode materials using M-2(OH)(2)(C8H4O4)-class metal-organic frameworks[J]. IONICS,2017,23(11):2969-2980. |
APA | Ren, Wenfeng,Yang, Shifeng,&Chen, Jian.(2017).Facile synthesis of spinel LiNi0.5Mn1.5O4 cathode materials using M-2(OH)(2)(C8H4O4)-class metal-organic frameworks.IONICS,23(11),2969-2980. |
MLA | Ren, Wenfeng,et al."Facile synthesis of spinel LiNi0.5Mn1.5O4 cathode materials using M-2(OH)(2)(C8H4O4)-class metal-organic frameworks".IONICS 23.11(2017):2969-2980. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论