Hydrothermal synthesis and structural characterization of a novel organic-inorganic hybrid compound {[Cu(2, 2 '-bpy)(2)](2)-Mo8O26}

	Hydrothermal synthesis and structural characterization of a novel organic-inorganic hybrid compound {[Cu(2, 2 '-bpy)(2)](2)-Mo8O26}
	Wang YH ; Chen LD ; Hu CW ; Wang EB ; Jia HQ ; Hu NH
刊名	chinese journal of chemistry
	2002
卷号	20 期号:1 页码:22-28
关键词	STATE COORDINATION CHEMISTRY TRANSITION-METAL COMPLEXES POLYOXOMOLYBDATE CLUSTERS CRYSTAL-STRUCTURES COMPOSITE-SOLIDS OXIDE CHAINS OCTAMOLYBDATE MOLYBDENUM SUBUNITS LIGANDS
ISSN号	1001-604x
通讯作者	hu cw
中文摘要	a novel organic-inorganic hybrid compound {[cu (2, 2'-bpy)(2)](2)mo8o26} has been hydrothermally synthesized and structurally characterized by single-crystal x-ray diffraction. the compound crystallizes in the orthorhombic space group, pna2(1), with a=2.4164 (5), b=1.8281 (4), c=1.1877 (2) nm, v=5.247(2) nm(3), z=4, and final r-1=0.0331, wr(2)=0.0727. the structure consists of discrete {[cu(2,2'-bpy)(2)](2)mo8o26} clusters, constructed from a beta -octamolybdate subunit[mo8o26](4-) covalently bonded to two [cu(2,2'-bpy)(2)](2+) coordination complex cations via bridging oxo groups. in addition, the spectroscopic properties and thermal behavior of this compound have been investigated by spectroscopic techniques (uv-vis, ir, raman and epr spectra) and tg analysis.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000173060000005
公开日期	2010-11-03
内容类型	期刊论文
源URL	[http://202.98.16.49/handle/322003/18851]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Wang YH,Chen LD,Hu CW,et al. Hydrothermal synthesis and structural characterization of a novel organic-inorganic hybrid compound {[Cu(2, 2 '-bpy)(2)](2)-Mo8O26}[J]. chinese journal of chemistry,2002,20(1):22-28.
APA	Wang YH,Chen LD,Hu CW,Wang EB,Jia HQ,&Hu NH.(2002).Hydrothermal synthesis and structural characterization of a novel organic-inorganic hybrid compound {[Cu(2, 2 '-bpy)(2)](2)-Mo8O26}.chinese journal of chemistry,20(1),22-28.
MLA	Wang YH,et al."Hydrothermal synthesis and structural characterization of a novel organic-inorganic hybrid compound {[Cu(2, 2 '-bpy)(2)](2)-Mo8O26}".chinese journal of chemistry 20.1(2002):22-28.