Evidence of "new hot spots'' from determining the nonlinear optical behavior of materials: mechanistic studies of the vanadium borate crystal, Na3VO2B6O11

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 中国科学院特殊环境功能材料与器件重点试验室

	Evidence of "new hot spots'' from determining the nonlinear optical behavior of materials: mechanistic studies of the vanadium borate crystal, Na3VO2B6O11
	Su, X (Su, Xin); Yang, ZH (Yang, Zhihua); Lee, MH (Lee, Ming-Hsien); Pan, SL (Pan, Shilie); Wang, Y (Wang, Ying); Fan, XY (Fan, Xiaoyun); Huang, ZJ (Huang, Zhenjun); Zhang, BB (Zhang, Bingbing)
刊名	PHYSICAL CHEMISTRY CHEMICAL PHYSICS
	2015
卷号	17 期号:7 页码:5338-5344
通讯作者	Yang, ZH
英文摘要	A novel mechanism for the nonlinear optical (NLO) effects of vanadium borate crystals, Na3VO2B6O11 (NVB), with distorted VO4 groups was investigated. A comprehensive analysis of the structure-property relationship was performed by combining the experimental measurements, the electronic structures calculations, the SHG-weighted electron density and the real-space atom-contribution analysis to yield the linear and nonlinear optical properties. The contribution of a (VO4)(3-) anionic group to the second harmonic generation (SHG) response was more pronounced than that of the (BO3)(3-) anionic group, which plays a virtual role in the SHG effects in NVB. The anionic (BO3)(3-) groups make dominant contributions to the birefringence, whereas the contribution of the V5+ cations to these linear optical effects is negligible.
收录类别	SCI
WOS记录号	WOS:000349616400062
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/4862]
专题	新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室新疆理化技术研究所_材料物理与化学研究室
作者单位	1.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Tamkang Univ, Dept Phys, Taipei 25137, Taiwan
推荐引用方式 GB/T 7714	Su, X ,Yang, ZH ,Lee, MH ,et al. Evidence of "new hot spots'' from determining the nonlinear optical behavior of materials: mechanistic studies of the vanadium borate crystal, Na3VO2B6O11[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2015,17(7):5338-5344.
APA	Su, X .,Yang, ZH .,Lee, MH .,Pan, SL .,Wang, Y .,...&Zhang, BB .(2015).Evidence of "new hot spots'' from determining the nonlinear optical behavior of materials: mechanistic studies of the vanadium borate crystal, Na3VO2B6O11.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,17(7),5338-5344.
MLA	Su, X ,et al."Evidence of "new hot spots'' from determining the nonlinear optical behavior of materials: mechanistic studies of the vanadium borate crystal, Na3VO2B6O11".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 17.7(2015):5338-5344.