Growth, Properties, and Theoretical Analysis of M2LiVO4 (M = Rb, Cs) Crystals: Two Potential Mid-Infrared Nonlinear Optical Materials

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 中国科学院特殊环境功能材料与器件重点试验室

	Growth, Properties, and Theoretical Analysis of M2LiVO4 (M = Rb, Cs) Crystals: Two Potential Mid-Infrared Nonlinear Optical Materials
	Han, GP (Han, Guopeng); Wang, Y (Wang, Ying); Su, X (Su, Xin); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
刊名	SCIENTIFIC REPORTS
	2017
卷号	7 期号:5
通讯作者	Wang, Y ; Pan, SL
英文摘要	Mid-Infrared nonlinear optical (Mid-IR NLO) crystals with excellent performances play a particularly important role for applications in areas such as telecommunications, laser guidance, and explosives detection. However, the design and growth of high performance Mid-IR NLO crystals with large NLO efficiency and high laser-damage threshold (LDT) still face numerous fundamental challenge. In this study, two potential Mid-IR NLO materials, Rb2LiVO4 (RLVO) and Cs2LiVO4 (CLVO) with noncentrosymmetric structures (Orthorhombic, Cmc2(1)) were synthesized by high-temperature solution method. Thermal analysis and powder X-ray diffraction demonstrate that RLVO and CLVO melt congruently. Centimeter sized crystals of CLVO have been grown by the top-seeded solution growth method. RLVO and CLVO exhibit strong second harmonic generation (SHG) effects (about 4 and 5 times that of KH2PO4, respectively) with a phase-matching behavior at 1.064 mu m, and a wide transparency range (0.33-6.0 mu m for CLVO). More importantly, RLVO and CLVO possess a high LDT value (similar to 28 x AgGaS2). In addition, the density functional theory (DFT) and dipole moments studies indicate that the VO4 anionic groups have a dominant contribution to the SHG effects in RLVO and CLVO. These results suggest that the title compounds are promising NLO candidate crystals applied in the Mid-IR region.
收录类别	SCI
WOS记录号	WOS:000401264400003
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/4791]
专题	新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室新疆理化技术研究所_材料物理与化学研究室
作者单位	1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Han, GP ,Wang, Y ,Su, X ,et al. Growth, Properties, and Theoretical Analysis of M2LiVO4 (M = Rb, Cs) Crystals: Two Potential Mid-Infrared Nonlinear Optical Materials[J]. SCIENTIFIC REPORTS,2017,7(5).
APA	Han, GP ,Wang, Y ,Su, X ,Yang, ZH ,&Pan, SL .(2017).Growth, Properties, and Theoretical Analysis of M2LiVO4 (M = Rb, Cs) Crystals: Two Potential Mid-Infrared Nonlinear Optical Materials.SCIENTIFIC REPORTS,7(5).
MLA	Han, GP ,et al."Growth, Properties, and Theoretical Analysis of M2LiVO4 (M = Rb, Cs) Crystals: Two Potential Mid-Infrared Nonlinear Optical Materials".SCIENTIFIC REPORTS 7.5(2017).