The Coulombic Nature of Active Nitrogen Sites in N-Doped Nanodiamond Revealed In Situ by Ionic Surfactants | |
Wu, Kuang-Hsu ; Lu, Yuefeng ; Luo, Jingjie ; Wang, Bolun ; Xu, Junyuan ; Cuong Pham-Huu ; Su, Dangsheng | |
刊名 | ACS CATALYSIS |
2017-05-01 | |
卷号 | 7期号:5页码:3295-3300 |
关键词 | Coulombic interaction in situ characterization ionic surfactant nitrogen-doped carbon nanodiamond oxygen reduction reaction |
ISSN号 | 2155-5435 |
通讯作者 | Su, DS (reprint author), Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China. ; Su, DS (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy DNL, Dalian 116023, Liaoning, Peoples R China. |
中文摘要 | The surface activity and charged nature of ionic surfactants (sodium dodecyl sulfate (SDS) and cetyltrimethylammonium bromide (CTAB)) are used as in situ probes for the Coulombic nature of active sites in N-doped nanocarbon. In this report, we demonstrate that, by selectively masking charge carrying sites, the active nitrogen sites in N-doped nanodiamond for oxygen reduction reaction are positively charged moieties, rather than those uncharged or negatively charged groups. From the N group analysis by X-ray photoelectron spectroscopy (XPS) and temperature-programmed desorption in a hydrogen gas atmosphere (H-2-TPD), we put forth the concern that the active nitrogen groups in N-doped nanocarbon may contain oxygen and should not be simply classified by the four conventional nitrogen types by XPS binding energy. |
学科主题 | Chemistry, Physical |
收录类别 | SCI |
资助信息 | Institute of Metal Research, Chinese Academy of Sciences; International Postdoctoral Exchange Scholar Fellowship from Chinese Academy of Sciences; PIFI Postdoctoral Research Fellowship from Chinese Academy of Sciences [2017PM0002] |
语种 | 英语 |
公开日期 | 2017-08-17 |
内容类型 | 期刊论文 |
源URL | [http://ir.imr.ac.cn/handle/321006/78158] |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | Wu, Kuang-Hsu,Lu, Yuefeng,Luo, Jingjie,et al. The Coulombic Nature of Active Nitrogen Sites in N-Doped Nanodiamond Revealed In Situ by Ionic Surfactants[J]. ACS CATALYSIS,2017,7(5):3295-3300. |
APA | Wu, Kuang-Hsu.,Lu, Yuefeng.,Luo, Jingjie.,Wang, Bolun.,Xu, Junyuan.,...&Su, Dangsheng.(2017).The Coulombic Nature of Active Nitrogen Sites in N-Doped Nanodiamond Revealed In Situ by Ionic Surfactants.ACS CATALYSIS,7(5),3295-3300. |
MLA | Wu, Kuang-Hsu,et al."The Coulombic Nature of Active Nitrogen Sites in N-Doped Nanodiamond Revealed In Situ by Ionic Surfactants".ACS CATALYSIS 7.5(2017):3295-3300. |
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