N-Heterocyclic carbene copper-catalyzed direct alkylation of terminal alkynes with non-activated alkyl triflates

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	N-Heterocyclic carbene copper-catalyzed direct alkylation of terminal alkynes with non-activated alkyl triflates
	Jin, Liqun 1,2; Hao, Wangfang 1; Xu, Jianeng 1; Sun N(孙楠)1; Hu BX(胡宝祥)1; Shen ZL(沈振陆)1; Mo WM(莫卫民)1; Hu XQ(胡信全)1,2
刊名	Chemical Communications
	2017
卷号	53 期号:29 页码:4124-4127
ISSN号	1359-7345
通讯作者	Jin, Liqun ; 胡信全
英文摘要	(NHC)-Cu-catalyzed C(sp)–C(sp³) bond formation has been successfully achieved under mild conditions. Nonactivated alkyl triflates, which could be easily derived from alcohols, were utilized as C–O electrophiles. Mechanistic studies suggested that copper acetylide was the active species. Scale-up reactions further demonstrated the practicality and efficiency of the developed strategy.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	National Natural Science Foundation of China (21603190;21473160;21376224);Jin alsothanks the support from Zhejiang University of Technology and Qianjiang Scholar Program funded by Zhejiang Province
语种	英语
WOS记录号	WOS:000399728000017
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/22178]
专题	兰州化学物理研究所_OSSO国家重点实验室
作者单位	1.Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310032, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Jin, Liqun,Hao, Wangfang,Xu, Jianeng,et al. N-Heterocyclic carbene copper-catalyzed direct alkylation of terminal alkynes with non-activated alkyl triflates[J]. Chemical Communications,2017,53(29):4124-4127.
APA	Jin, Liqun.,Hao, Wangfang.,Xu, Jianeng.,Sun N.,Hu BX.,...&Hu XQ.(2017).N-Heterocyclic carbene copper-catalyzed direct alkylation of terminal alkynes with non-activated alkyl triflates.Chemical Communications,53(29),4124-4127.
MLA	Jin, Liqun,et al."N-Heterocyclic carbene copper-catalyzed direct alkylation of terminal alkynes with non-activated alkyl triflates".Chemical Communications 53.29(2017):4124-4127.