The synergy between atomically dispersed Pd and cerium oxide for enhanced catalytic properties

CORC > 兰州化学物理研究所 > 中国科学院兰州化学物理研究所 > 苏州研究院

	The synergy between atomically dispersed Pd and cerium oxide for enhanced catalytic properties
	Wang X(王雪)1,2; Chen, Jiayu 1; Zeng, Jianxin 1; Wang, Qiuxiang 1; Li, Zejun 3; Qin, Ruixuan 1; Wu, Changzheng 3; Xie, Zhaoxiong 1; Zheng, Lansun 1
刊名	Nanoscale
	2017
卷号	9 期号:20 页码:6643-6648
ISSN号	2040-3364
通讯作者	王雪 ; Xie, Zhaoxiong
英文摘要	We report a photochemical synthesis of Pd/CeO₂ catalysts with atomically dispersed Pd. Compared to atomically dispersed Pd/CeO₂ with a cubic CeO₂ support (Pd/CeO₂-CP), atomically dispersed Pd/CeO₂ with a truncated octahedral CeO₂ support (Pd/CeO₂-TOP) exhibited higher activity and selectivity, owing to the synergy between Pd atoms and the (111) surface of CeO₂. When compared to Pd/CeO₂ with Pd clusters and nanoparticles via chemical reduction, Pd/CeO₂-TOP showed excellent activity with an enhancement factor of 324 in CO oxidation, as well as an activity enhancement by a factor of 344 in selective oxidation of benzyl alcohol.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the National Basic Research Program of China (grant no. 2015CB932301);the National Natural Science Foundation of China (grant no. 21333008)
语种	英语
WOS记录号	WOS:000402034400004
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/21988]
专题	兰州化学物理研究所_苏州研究院兰州化学物理研究所_OSSO国家重点实验室
作者单位	1.State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, P. R. China 2.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, P. R. China 3.Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, Hefei Science Center (CAS), and CAS Key Laboratory of Mechanical Behavior and Design of Materials, University of Science and Technology of China, Hefei, P. R. China 4.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Collaborat Innovat Ctr Chem Energy Mat, Hefei Sci Ctr CAS, Hefei 230026, Peoples R China 5.Univ Sci & Technol China, CAS Key Lab Mech Behav & Design Mat, Hefei 230026, Peoples R China
推荐引用方式 GB/T 7714	Wang X,Chen, Jiayu,Zeng, Jianxin,et al. The synergy between atomically dispersed Pd and cerium oxide for enhanced catalytic properties[J]. Nanoscale,2017,9(20):6643-6648.
APA	Wang X.,Chen, Jiayu.,Zeng, Jianxin.,Wang, Qiuxiang.,Li, Zejun.,...&Zheng, Lansun.(2017).The synergy between atomically dispersed Pd and cerium oxide for enhanced catalytic properties.Nanoscale,9(20),6643-6648.
MLA	Wang X,et al."The synergy between atomically dispersed Pd and cerium oxide for enhanced catalytic properties".Nanoscale 9.20(2017):6643-6648.