Inhibition of photocorrosion of CdS via assembling with thin film TiO2 and removing formed oxygen by artificial gill for visible light overall water splitting
Ning XF(宁晓峰)1,2; Li, Jian3; Yang BJ(杨宝军)1; Zhen WL(甄文龙)1; Li Z(李振)1; Tian B(田彬)1; Lu GX(吕功煊)1
刊名Applied Catalysis B: Environmental
2017
卷号212页码:129-139
关键词Inhibition of CdS photocorrosion Inhibition H2 and O2 back TiO2 thin film loading Overall water splitting Artificial gill
ISSN号0926-3373
通讯作者吕功煊
英文摘要

CdS is a well-known and important visible-light responsive photocatalyst for overall water splitting. However, the serious photocorrosion property limits its application in photocatalysis. Through modification TiO2 thin film over CdS surface, TiO2/CdS photocatalyst exhibited an obviously enhanced photocatalytic stability. The H2 evolution rate (3.074 μmol h−1 g−1) of modified Pt-TiO2/CdS under visible light toward overall water splitting was almost 6 times higher than that of CdS sample (0.534 μmol h−1 g−1). The application of artificial gill in photocatalytic overall water splitting system removed the newly formed oxygen from catalyst surface mainly inhibiting the hydrogen and oxygen back recombination to water and preventing the oxygen led oxidation or photocorrosion. By these two strategies, we fulfilled visible light induced overall water splitting in CdS dispersion and achieved satisfied stability during reaction.

学科主题物理化学与绿色催化
收录类别SCI
资助信息the National Natural Science Foundation of China (Grant No. 21433007;21673262);the 973 Program of Department of Sciences and Technology China (Grant No. 2013CB632404)
语种英语
WOS记录号WOS:000401134200015
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/21892]  
专题兰州化学物理研究所_OSSO国家重点实验室
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.China Astronaut Res & Training Ctr, Beijing 100094, Peoples R China
推荐引用方式
GB/T 7714
Ning XF,Li, Jian,Yang BJ,et al. Inhibition of photocorrosion of CdS via assembling with thin film TiO2 and removing formed oxygen by artificial gill for visible light overall water splitting[J]. Applied Catalysis B: Environmental,2017,212:129-139.
APA Ning XF.,Li, Jian.,Yang BJ.,Zhen WL.,Li Z.,...&Lu GX.(2017).Inhibition of photocorrosion of CdS via assembling with thin film TiO2 and removing formed oxygen by artificial gill for visible light overall water splitting.Applied Catalysis B: Environmental,212,129-139.
MLA Ning XF,et al."Inhibition of photocorrosion of CdS via assembling with thin film TiO2 and removing formed oxygen by artificial gill for visible light overall water splitting".Applied Catalysis B: Environmental 212(2017):129-139.
个性服务
查看访问统计
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。


©版权所有 ©2017 CSpace - Powered by CSpace