Stereoselective Synthesis of trans-2-thien-alpha-oyl-3-[(un)substituted phenyl]-4-acetyl-5-methyl-2,3-dihydrofurans

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	Stereoselective Synthesis of trans-2-thien-alpha-oyl-3-[(un)substituted phenyl]-4-acetyl-5-methyl-2,3-dihydrofurans
	Jiang HY(姜海燕) ; Cao WG(曹卫国) ; Zhang H(张慧) ; Sun RS(孙汝淑) ; Chen J(陈杰) ; Deng HM(邓红梅) ; Shao M(邵敏) ; Zhu SZ(朱仕正)
刊名	Chin. J. Chem.
	2008
卷号	26 期号:4 页码:736-740
ISSN号	1001-604X
其他题名	Stereoselective Synthesis of trans-2-thien-alpha-oyl-3-[(un)substituted phenyl]-4-acetyl-5-methyl-2,3-dihydrofurans
通讯作者	曹卫国 ; 朱仕正
英文摘要	Trans-2-thien-alpha-oyl-3-[(un)substituted phenyl]-4-acetyl-5-methyl-2,3-dihydrofurans 3 were prepared in good yields with high stereoselectivity by the reaction of thien-alpha-oylmethyltriphenylarsonium bromide 1 with 3-[(un)substituted benzylidene]-2,4-pentadione 2 in benzene in the presence of potassium carbonate at 55 degrees C. The structure of compound 3 was confirmed by IR, MS, H-1 NMR, H-1-H-1 COSY, microanalysis and single crystal X-ray diffraction analysis. The possible reaction mechanism for the formation of products was also proposed.
学科主题	有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/cjoc.200890137
语种	英语
WOS记录号	WOS:000255532800027
公开日期	2013-01-18
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/14450]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
推荐引用方式 GB/T 7714	Jiang HY,Cao WG,Zhang H,et al. Stereoselective Synthesis of trans-2-thien-alpha-oyl-3-[(un)substituted phenyl]-4-acetyl-5-methyl-2,3-dihydrofurans[J]. Chin. J. Chem.,2008,26(4):736-740.
APA	姜海燕.,曹卫国.,张慧.,孙汝淑.,陈杰.,...&朱仕正.(2008).Stereoselective Synthesis of trans-2-thien-alpha-oyl-3-[(un)substituted phenyl]-4-acetyl-5-methyl-2,3-dihydrofurans.Chin. J. Chem.,26(4),736-740.
MLA	姜海燕,et al."Stereoselective Synthesis of trans-2-thien-alpha-oyl-3-[(un)substituted phenyl]-4-acetyl-5-methyl-2,3-dihydrofurans".Chin. J. Chem. 26.4(2008):736-740.