| Dawson型磷钨酸盐与混合配体桥连的四核Cu-Phen配合物构筑的杂化物; Construction of Organic-Inorganic Hybrid from Dawson-Type Tungstophosphate and Tetranuclear Copper Complex | |
| 孙岳 ; 张先徽 ; 那延祥 ; 李昌立 ; 冯克成 | |
| 2013-12-10 | |
| 关键词 | 无机-有机杂化化合物 Dawson型多金属氧酸盐 四核铜配合物 对苯二甲酸连接体 电化学性质 organic-inorganic hybrid dawson-type POM tetranuclear copper complex 1 4-bdc linkage electrocatalytic property |
| 英文摘要 | 通过水热合成得到了一个新颖的包含四核铜配合物的无机-有机杂化化合物[CuCl(H2O)4)][CuCl(H2O)(PHEn)][{(CuPHEn)2Cl2}2(bdC)]2[P2W18O62]·5H2O(1)(PHEn=1,10-PHEnAnTHrOlInE和bdC=1,4-bEnzEnEdICArbOXylATE),对其进行了元素分析、红外光谱、热重、电化学等表征,并用X-射线单晶衍射测定了它的晶体结构。化合物1含有由Cl和bdC桥连的四核铜配合物阳离子[{(CuPHEn)2Cl2}2(bdC)]2+。此外,化合物1的电化学研究表明其对亚硝酸的还原具有很好的电催化活性。; A novel hybrid compound [CuCl(H2O)4)] [CuCl(H2O)(Phen)] [{(CuPhen)2Cl2}2(bdc)]2[P2W18O62]·5H2O(1)(Phen=1,10-phenanthroline and bdc=1,4-benzenedicarboxylate), containing multinuclear CuⅡcomplex cations, has been obtained in hydrothermal conditions and characterized by IR, elemental, thermogravimetric, electrochemical and single-crystal X-ray diffraction analysis.The main structural feature to this compound is the copper-Phen complex moieties which compose new tetranuclear copper-Phen complex cation [{(CuPhen)2Cl2}2(bdc)]2+bridged by Cl and bdc ligands.Furthermore, a compound 1-modiffied carbon paste electrode(1-CPE) displays the good electrocatalytic activity toward the reduction of nitrite.CCDC: 952036. |
| 语种 | zh_CN |
| 内容类型 | 期刊论文 |
| 源URL | [http://dspace.xmu.edu.cn/handle/2288/105596]  |
| 专题 | 航空航天－已发表论文 |
| 推荐引用方式 GB/T 7714 | 孙岳,张先徽,那延祥,等. Dawson型磷钨酸盐与混合配体桥连的四核Cu-Phen配合物构筑的杂化物, Construction of Organic-Inorganic Hybrid from Dawson-Type Tungstophosphate and Tetranuclear Copper Complex[J],2013. |
| APA | 孙岳,张先徽,那延祥,李昌立,&冯克成.(2013).Dawson型磷钨酸盐与混合配体桥连的四核Cu-Phen配合物构筑的杂化物.. |
| MLA | 孙岳,et al."Dawson型磷钨酸盐与混合配体桥连的四核Cu-Phen配合物构筑的杂化物".(2013). |
| 个性服务 |
| 查看访问统计 |
| 相关权益政策 |
| 暂无数据 |
| 收藏/分享 |
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。
修改评论