Hydrothermal synthesis and characterization of microporous crystals of trivalent metal-containing zirconium phosphates

	Hydrothermal synthesis and characterization of microporous crystals of trivalent metal-containing zirconium phosphates
	Sun, ZG ; Liu, ZM ; Xu, L ; Yang, Y ; He, YL
刊名	catalysis today
	2004-09-01
卷号	93-5 期号:93－95 页码:639-643
关键词	hydrothermal synthesis zirconium phosphates (P-31 Al-27) MAS NMR
产权排序	1;1
英文摘要	two organically templated trivalent metal-containing crystalline zirconium phosphate materials fezrpo-8 and alzrpo-8 have been prepared hydrothermally by using fluoride as a mineralizer, and 1,6-diaminohexane (dah) as templates. the powder xrd patterns indicate that the as-synthesized products are new materials. substitutions of al3+ or fe3+ into zr4+ sites were confirmed by a combination of powder x-ray diffraction (xrd) and nuclear magnetic resonance (nmr) studies. the thermal behavior of the title compounds have been investigated using tg-dta and x-ray thermodiffractometry, which indicated that the inorganic framework of the compounds are thermally stable up to similar to400 degreesc. (c) 2004 elsevier b.v. all rights reserved.
WOS标题词	science & technology ; physical sciences ; technology
类目[WOS]	chemistry, applied ; chemistry, physical ; engineering, chemical
研究领域[WOS]	chemistry ; engineering
关键词[WOS]	p-31 nmr ; titanium phosphates ; open-framework ; x-ray ; ethylenediamine ; conductors ; fluorides ; al-27
收录类别	SCI ; ISTP
原文出处	true
语种	英语
WOS记录号	WOS:000223973200091
公开日期	2010-11-30
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/81813]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dept Nat Gas Chem & Appl Catalysis, Dalian 116023, Peoples R China 2.Liaoning Normal Univ, Dept Chem, Dalian 116029, Peoples R China
推荐引用方式 GB/T 7714	Sun, ZG,Liu, ZM,Xu, L,et al. Hydrothermal synthesis and characterization of microporous crystals of trivalent metal-containing zirconium phosphates[J]. catalysis today,2004,93-5(93－95):639-643.
APA	Sun, ZG,Liu, ZM,Xu, L,Yang, Y,&He, YL.(2004).Hydrothermal synthesis and characterization of microporous crystals of trivalent metal-containing zirconium phosphates.catalysis today,93-5(93－95),639-643.
MLA	Sun, ZG,et al."Hydrothermal synthesis and characterization of microporous crystals of trivalent metal-containing zirconium phosphates".catalysis today 93-5.93－95(2004):639-643.