Composite PET Membrane with Nanostructured Ag/AgTCNQ Schottky Junctions: Electrochemical Nanofabrication and Charge-Transfer Properties

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	Composite PET Membrane with Nanostructured Ag/AgTCNQ Schottky Junctions: Electrochemical Nanofabrication and Charge-Transfer Properties
	Huang, Li ; Chen, Yong ; Bian, Shujuan ; Huang, Yi-Fan ; Tian, Zhong-Qun ; Zhan, Dongping ; Tian ZQ(田中群) ; Zhan DP(詹东平)
刊名	http://dx.doi.org/10.1002/chem.201303391
	2014-01-13
关键词	LIQUID-LIQUID INTERFACE IMMISCIBLE ELECTROLYTE-SOLUTIONS LIQUID/LIQUID INTERFACES AG-TCNQ WATER/1,2-DICHLOROETHANE INTERFACE POTENTIAL DIFFERENCE POLARIZED INTERFACE MAGNETIC-PROPERTIES GOLD NANOPARTICLES CHEMICAL-REACTION
英文摘要	National Science Foundation of China [21061120456, 21005049, 21021002, 20973142]; National Basic Research Program of China [2012CB93290, 2011CB933700]; Natural Science Foundation of Fujian Province of China [2012J06004]; Program for New Century Excellent Talents in University [NCET-12-0318]; Large-area nanostructured Ag/Ag-tetracyanoquinodimethane (TCNQ) Schottky junctions are fabricated electrochemically on a mesoporous polyethylene terephthalate (PET) membrane-supported water/1, 2-dichloroethane (DCE) interface. When the interface is polarized, Ag+ ions transfer across the PET membrane from the aqueous phase and are reduced to form metallic Ag on the PET membrane, which reacts further with tetracyanoquinodimethane (TCNQ) in the DCE phase to form nanostructured Ag/AgTCNQ Schottky junctions. Once the mesoporous membrane is blocked by metallic Ag, a bipolar mechanism is proposed to explain the successive growth of AgTCNQ nanorods and Ag film on each side of the PET membrane. Due to the well-formed nanostructure of Ag/AgTCNQ Schottky junctions, the direct electrochemical behavior is observed, which is essential to explain the physicochemical mechanism of its electric performance. Moreover, the composite PET membrane with nanostructured Ag/AgTCNQ Schottky junctions is tailorable and can be assembled directly into electric devices without any pretreatment.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/89413]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Huang, Li,Chen, Yong,Bian, Shujuan,et al. Composite PET Membrane with Nanostructured Ag/AgTCNQ Schottky Junctions: Electrochemical Nanofabrication and Charge-Transfer Properties[J]. http://dx.doi.org/10.1002/chem.201303391,2014.
APA	Huang, Li.,Chen, Yong.,Bian, Shujuan.,Huang, Yi-Fan.,Tian, Zhong-Qun.,...&詹东平.(2014).Composite PET Membrane with Nanostructured Ag/AgTCNQ Schottky Junctions: Electrochemical Nanofabrication and Charge-Transfer Properties.http://dx.doi.org/10.1002/chem.201303391.
MLA	Huang, Li,et al."Composite PET Membrane with Nanostructured Ag/AgTCNQ Schottky Junctions: Electrochemical Nanofabrication and Charge-Transfer Properties".http://dx.doi.org/10.1002/chem.201303391 (2014).