Solvothermal Synthesis of Four Polyoxometalate-Based Coordination Polymers Including Diverse Ag(I)center dot center dot center dot pi Interactions

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	Solvothermal Synthesis of Four Polyoxometalate-Based Coordination Polymers Including Diverse Ag(I)center dot center dot center dot pi Interactions
	Liang, Min-Xia ; Ruan, Chan-Zi ; Sun, Di ; Kong, Xiang-Jian ; Ren, Yan-Ping ; Long, La-Sheng ; Huang, Rong-Bin ; Zheng, Lan-Sun ; Kong XJ(孔祥建) ; Ren YP(任艳平) ; Long LS(龙腊生) ; Huang RB(黄荣彬) ; Zheng LS(郑兰荪)
刊名	http://dx.doi.org/10.1021/ic4022596
	2014-01-20
关键词	METAL-ORGANIC FRAMEWORKS POLYCYCLIC AROMATIC-COMPOUNDS PI-PI INTERACTIONS SILVER(I) COMPLEXES CRYSTAL-STRUCTURES CONSTRUCTION CHEMISTRY LIGAND KEGGIN SANDWICH
英文摘要	NNSFC [21071119, 21371144, 90922031]; 973 project from MSTC [2012CB821704]; Key Laboratory of Polyoxometalates Science of Ministry of Education; Four 3D POM-based silver coordination polymers, namely, [Ag-17(ptz)(11)(PW12O40)(2)](n) (1), [Ag-17(ptz)(11)(PMo12O40)(2)](n) (2), [Ag-12(ptz)(6)(CN)(2)(SiW12O40)](n) (3), and [Ag-19(ptz)(8)(H(2)ptz)(H(3)ptz)(AgP5W30O110)center dot 7H(2)O]n (4), have been obtained by solvothermal reaction of AgNO3 and 5-phenyl-1H-tetrazole (Hptz) ligand in the presence of four types of polyoxometalates. Structural analysis shows that four types of Ag(I)center dot center dot center dot pi interactions, m-eta(l), m/p-eta(2), o/m-eta(2), and o/m/p-eta(3), were observed in compounds 1-4, depending on the polyoxometalates used. The in situ generated CN- ion in compound 3 shows unprecedented mixed sigma and pi bonding modes, similar to the C-2(2-) ion in well-studied silver acetylides. For 4, the Na+ ion in the Preyssler heteropolyoxoanion, [NaP5W30O110](14-), was exchanged by Ag(I) under solvothermal conditions; generating a novel [AgP5W30O110](14-) anion. In addition, the photoluminescence behavior of 1-4 was also investigated.
语种	英语
出版者	AMER CHEMICAL SOC
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/89411]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Liang, Min-Xia,Ruan, Chan-Zi,Sun, Di,et al. Solvothermal Synthesis of Four Polyoxometalate-Based Coordination Polymers Including Diverse Ag(I)center dot center dot center dot pi Interactions[J]. http://dx.doi.org/10.1021/ic4022596,2014.
APA	Liang, Min-Xia.,Ruan, Chan-Zi.,Sun, Di.,Kong, Xiang-Jian.,Ren, Yan-Ping.,...&郑兰荪.(2014).Solvothermal Synthesis of Four Polyoxometalate-Based Coordination Polymers Including Diverse Ag(I)center dot center dot center dot pi Interactions.http://dx.doi.org/10.1021/ic4022596.
MLA	Liang, Min-Xia,et al."Solvothermal Synthesis of Four Polyoxometalate-Based Coordination Polymers Including Diverse Ag(I)center dot center dot center dot pi Interactions".http://dx.doi.org/10.1021/ic4022596 (2014).