Electron-Deficient Poly(p-phenylene vinylene) Provides Electron Mobility over 1 cm2 V-1 s-1 under Ambient Conditions

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	Electron-Deficient Poly(p-phenylene vinylene) Provides Electron Mobility over 1 cm2 V-1 s-1 under Ambient Conditions
	Lei, Ting ; Dou, Jin-Hu ; Cao, Xiao-Yu ; Wang, Jie-Yu ; Pei, Jian ; Cao XY(曹晓宇)
刊名	http://dx.doi.org/10.1021/ja403624a
	2013-08-21
关键词	Polymers
英文摘要	Poly(p-phenylene vinylene) derivatives (PPVs) are one of the most widely investigated p-type polymers in organic electronics. PPVs generally exhibit electron mobilities lower than 10-4 cm2 V-1 s-1, thus hindering their applications in high-performance polymer field-effect transistors and organic photovoltaics. Herein, we design and synthesize a novel electron-deficient PPV derivative, benzodifurandione-based PPV (BDPPV). This new PPV derivative displays high electron mobilities up to 1.1 cm2 V-1 s-1 under ambient conditions (4 orders of magnitude higher than those of other PPVs), because it overcomes common defects in PPVs, such as conformational disorder, weak interchain interaction, and a high LUMO level. BDPPV represents the first polymer that can transport electrons over 1 cm2 V-1 s-1 under ambient conditions. ? 2013 American Chemical Society.
语种	英语
出版者	American Chemical Society
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/89188]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Lei, Ting,Dou, Jin-Hu,Cao, Xiao-Yu,et al. Electron-Deficient Poly(p-phenylene vinylene) Provides Electron Mobility over 1 cm2 V-1 s-1 under Ambient Conditions[J]. http://dx.doi.org/10.1021/ja403624a,2013.
APA	Lei, Ting,Dou, Jin-Hu,Cao, Xiao-Yu,Wang, Jie-Yu,Pei, Jian,&曹晓宇.(2013).Electron-Deficient Poly(p-phenylene vinylene) Provides Electron Mobility over 1 cm2 V-1 s-1 under Ambient Conditions.http://dx.doi.org/10.1021/ja403624a.
MLA	Lei, Ting,et al."Electron-Deficient Poly(p-phenylene vinylene) Provides Electron Mobility over 1 cm2 V-1 s-1 under Ambient Conditions".http://dx.doi.org/10.1021/ja403624a (2013).