Supported monodisperse Pt nanoparticles from [Pt3(CO) 3(μ2-CO)3]52- clusters for investigating support-Pt interface effect in catalysis | |
Chen, Guangxu ; Yang, Huayan ; Wu, Binghui ; Zheng, Yanping ; Zheng, Nanfeng ; Zheng NF(郑南峰) | |
刊名 | http://dx.doi.org/10.1039/c3dt50942g |
2013-09-21 | |
关键词 | Catalysis Nanoparticles |
英文摘要 | Here we present a surfactant-free strategy to prepare supported monodisperse Pt nanoparticles from molecular [Pt3(CO) 3(μ2-CO)3]52- clusters. The strategy allows facile deposition of same-sized Pt nanoparticles on various oxide supports to unambiguously study the interface effect between noble metal and metal oxide in catalysis. In this study, Fe2O 3 is demonstrated to be a superior support over TiO2, CeO2 and SiO2 to prepare highly active supported Pt nanoparticles for CO oxidation, which indicates that the interfaces between Pt and iron oxide are the active sites for O2 activation and CO oxidation. ? 2013 The Royal Society of Chemistry. |
语种 | 英语 |
出版者 | Royal Society of Chemistry |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/89183] |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Chen, Guangxu,Yang, Huayan,Wu, Binghui,et al. Supported monodisperse Pt nanoparticles from [Pt3(CO) 3(μ2-CO)3]52- clusters for investigating support-Pt interface effect in catalysis[J]. http://dx.doi.org/10.1039/c3dt50942g,2013. |
APA | Chen, Guangxu,Yang, Huayan,Wu, Binghui,Zheng, Yanping,Zheng, Nanfeng,&郑南峰.(2013).Supported monodisperse Pt nanoparticles from [Pt3(CO) 3(μ2-CO)3]52- clusters for investigating support-Pt interface effect in catalysis.http://dx.doi.org/10.1039/c3dt50942g. |
MLA | Chen, Guangxu,et al."Supported monodisperse Pt nanoparticles from [Pt3(CO) 3(μ2-CO)3]52- clusters for investigating support-Pt interface effect in catalysis".http://dx.doi.org/10.1039/c3dt50942g (2013). |
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