Synthesis and crystal structure of an Ag-20 cluster incorporating in situ generated bipodal ArP(OEt)S-2 (-) and tripodal ArPOS2 (2-) ligands (Ar=4-methoxyphenyl)

CORC > 厦门大学 > 化学化工－已发表论文

	Synthesis and crystal structure of an Ag-20 cluster incorporating in situ generated bipodal ArP(OEt)S-2 (-) and tripodal ArPOS2 (2-) ligands (Ar=4-methoxyphenyl)
	Sun, D. ; Wei, Z. H. ; Yang, C. F. ; Zhang, N. ; Huang, R. B. ; Zheng, L. S. ; Huang RB(黄荣彬)
刊名	http://dx.doi.org/10.1016/j.inoche.2010.06.048
	2010-10
关键词	X-RAY-STRUCTURE LAWESSONS REAGENT CHALCOGENIDE CLUSTERS METAL-COMPLEXES ROUTE THIOESTERS CHEMISTRY THIATION ANIONS
英文摘要	National Natural Science Foundation of China [20721001]; MSTC [2007CB815301]; National Science Fund of China for Fostering Talents in Basic Science [J0630429]; The ultrasonic reaction of Lawesson's reagent (2,4-bis(4-methoxyphenyl)-1,3-dithiadiphosphetane-2,4-disulfide, LR) with Ag(OAc) and Ph3P (triphenylphosphane) gave an Ag-20 cluster {[Ag-20(ArP(OEt)S-2)(6) (ArPOS2)(6)(Ph3P)(8)]center dot 2(OAc)center dot 8(H2O)center dot(CHCl3)} (1) (Ar = 4-methoxyphenyl). The core of this cluster is an Ag-based propeller comprised of one triangle central axis and three distorted rectangle leaves. The bipodal and tripodal P/S-containing ligands were generated from in situ P-S bond cleavage and P-O bond formation process. (C) 2010 Elsevier B.V. All rights reserved.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/64636]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Sun, D.,Wei, Z. H.,Yang, C. F.,et al. Synthesis and crystal structure of an Ag-20 cluster incorporating in situ generated bipodal ArP(OEt)S-2 (-) and tripodal ArPOS2 (2-) ligands (Ar=4-methoxyphenyl)[J]. http://dx.doi.org/10.1016/j.inoche.2010.06.048,2010.
APA	Sun, D..,Wei, Z. H..,Yang, C. F..,Zhang, N..,Huang, R. B..,...&黄荣彬.(2010).Synthesis and crystal structure of an Ag-20 cluster incorporating in situ generated bipodal ArP(OEt)S-2 (-) and tripodal ArPOS2 (2-) ligands (Ar=4-methoxyphenyl).http://dx.doi.org/10.1016/j.inoche.2010.06.048.
MLA	Sun, D.,et al."Synthesis and crystal structure of an Ag-20 cluster incorporating in situ generated bipodal ArP(OEt)S-2 (-) and tripodal ArPOS2 (2-) ligands (Ar=4-methoxyphenyl)".http://dx.doi.org/10.1016/j.inoche.2010.06.048 (2010).