Asymmetric Synthesis of Both Enantiomers of Disparlure

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	Asymmetric Synthesis of Both Enantiomers of Disparlure
	Wang Zhigang ; Zheng Jianfeng ; Huang Peiqiang ; Huang PQ(黄培强)
刊名	http://dx.doi.org/10.1002/cjoc.201100482
	2012-01
关键词	GYPSY-MOTH PHEROMONE 6-METHYLHEPTYL PHENYL SULFONE OPTICALLY-ACTIVE DISPARLURE SALTMARSH CATERPILLAR MOTH CHIRAL EPOXY ALCOHOLS SEX-PHEROMONE ALPHA,BETA-EPOXY SULFOXIDES ENANTIODIVERGENT SYNTHESIS STEREOSELECTIVE SYNTHESIS SHARPLESS EPOXIDATION
英文摘要	National Basic Research Program (973 Program) of China [2010CB833200]; National Natural Science Foundation of China [20832005]; Natural Science Foundation of Fujian Province of China [2011J01054]; Starting from propargyl alcohol (12), and on the basis of Zhou's modified Sharpless asymmetric epoxidation, the sex pheromone of the Gypsy moth, disparlure (+)-8 and its enantiomer (-)-8 have been synthesized, each in six steps, with overall yields of 29% for (+)-8 and 27% for (-)-8 (ee>98%). The use of the sequential coupling tactic renders the method flexible, which is applicable to the synthesis of other cis-epoxy pheromones.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/64440]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Wang Zhigang,Zheng Jianfeng,Huang Peiqiang,et al. Asymmetric Synthesis of Both Enantiomers of Disparlure[J]. http://dx.doi.org/10.1002/cjoc.201100482,2012.
APA	Wang Zhigang,Zheng Jianfeng,Huang Peiqiang,&黄培强.(2012).Asymmetric Synthesis of Both Enantiomers of Disparlure.http://dx.doi.org/10.1002/cjoc.201100482.
MLA	Wang Zhigang,et al."Asymmetric Synthesis of Both Enantiomers of Disparlure".http://dx.doi.org/10.1002/cjoc.201100482 (2012).