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	Highly enantioselective transfer hydrogenation of aromatic ketones catalyzed by chiral diaminodiphosphine-iridium(I) complexes
	Tang, C. L. ; Li, Y. Y. ; Pan, E. D. ; Zhang, H. ; Zhou, Z. H. ; Gao, J. X. ; Gao JX(高景星)
	2001
关键词	ASYMMETRIC TRANSFER HYDROGENATION LIGANDS
英文摘要	Enantioselective transfer hydrogenation of a range of aromatic ketones in 2 - propanol catalyzed by chiral Ir(I) complexes, prepared in situ from [ Ir(COD) Cl](2) and C-2(-) symmetric diaminodiphosphine ligand. The complex acts as an excellent catalyst precursor in asymmetric transfer hydrogenation of isobutyrophenone. leading to optically active alcohol up to 98% yield and 98% ee after 4 h at 25 degreesC (S/C = 1200).
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/64316]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Tang, C. L.,Li, Y. Y.,Pan, E. D.,et al. Highly enantioselective transfer hydrogenation of aromatic ketones catalyzed by chiral diaminodiphosphine-iridium(I) complexes[J],2001.
APA	Tang, C. L..,Li, Y. Y..,Pan, E. D..,Zhang, H..,Zhou, Z. H..,...&高景星.(2001).Highly enantioselective transfer hydrogenation of aromatic ketones catalyzed by chiral diaminodiphosphine-iridium(I) complexes..
MLA	Tang, C. L.,et al."Highly enantioselective transfer hydrogenation of aromatic ketones catalyzed by chiral diaminodiphosphine-iridium(I) complexes".(2001).

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