Hydrothermal synthesis and crystal structures of three-dimensional co-ordination frameworks constructed with mixed terephthalate (tp) and 4,4 '-bipyridine (4,4 '-bipy) ligands: M(tp)(4,4 '-bipy) (M = Co-II, Cd-II or Zn-II)

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	Hydrothermal synthesis and crystal structures of three-dimensional co-ordination frameworks constructed with mixed terephthalate (tp) and 4,4 '-bipyridine (4,4 '-bipy) ligands: M(tp)(4,4 '-bipy) (M = Co-II, Cd-II or Zn-II)
	Tao, J. ; Tong, M. L. ; Chen, X. M. ; Tao J(陶军)
刊名	http://dx.doi.org/10.1039/b005438k
	2013-12-12
关键词	ORGANIC COORDINATION FRAMEWORKS MAGNETIC-PROPERTIES METAL-COMPLEXES DINUCLEAR COMPLEXES POROUS SOLIDS POLYMERS COPPER(II) NETWORKS CHAINS IONS
英文摘要	Three new metal-organic co-ordination frameworks formulated as [M(tp)(4,4'-bipy)] [M = Co-II 1, Cd-II 2 or Zn-II 3; tp = terephthalate; 4,4'-bipy = 4,4'-bipyridine] have been hydrothermally prepared and structurally characterized. Each pair of metal atoms in the three compounds are bridged by bis-bidentate or chelating/bridging bis-bidentate tp ligands to form a linear or zigzag co-ordination chain, and adjacent chains are further linked by chelating or monodentate bis-bidentate tp ligands to form two-dimensional rectangular or parallelogram-like [M(tp)] sheets with dimensions of 10.30 x 11.37, 10.08 x 11.68 and 10.28 x 10.98 Angstrom for complexes 1, 2 and 3, respectively. Adjacent sheets are pillared by 4,4'-bipy spacers into a three-dimensional co-ordination network through the covalently linking mode of ... 4,4'-bipy-M-II-4,4'-bipy-M-II..., which feature cuboidal [M-16(tp)(8)(4,4'-bipy)(8)] structural units. Twofold interpenetration of the above three-dimensional co-ordination networks results in stable crystal structures of the three compounds.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/64272]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Tao, J.,Tong, M. L.,Chen, X. M.,et al. Hydrothermal synthesis and crystal structures of three-dimensional co-ordination frameworks constructed with mixed terephthalate (tp) and 4,4 '-bipyridine (4,4 '-bipy) ligands: M(tp)(4,4 '-bipy) (M = Co-II, Cd-II or Zn-II)[J]. http://dx.doi.org/10.1039/b005438k,2013.
APA	Tao, J.,Tong, M. L.,Chen, X. M.,&陶军.(2013).Hydrothermal synthesis and crystal structures of three-dimensional co-ordination frameworks constructed with mixed terephthalate (tp) and 4,4 '-bipyridine (4,4 '-bipy) ligands: M(tp)(4,4 '-bipy) (M = Co-II, Cd-II or Zn-II).http://dx.doi.org/10.1039/b005438k.
MLA	Tao, J.,et al."Hydrothermal synthesis and crystal structures of three-dimensional co-ordination frameworks constructed with mixed terephthalate (tp) and 4,4 '-bipyridine (4,4 '-bipy) ligands: M(tp)(4,4 '-bipy) (M = Co-II, Cd-II or Zn-II)".http://dx.doi.org/10.1039/b005438k (2013).