Copper-catalyzed selective oxidation of methane to formaldehyde by oxygen

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	Copper-catalyzed selective oxidation of methane to formaldehyde by oxygen
	LI, Y ; CHEN, SL ; ZHANG, QH ; WANG, Y ; Wang Y(王野)
刊名	http://dx.doi.org/10.1246/cl.2006.572
	2006-06-05
关键词	IRON PHOSPHATE CATALYST OXIDE PERFORMANCE
英文摘要	Cu/SBA-15 exhibited the highest activity for the selective oxidation of methane to formaldehyde by oxygen among various M/SBA-15 catalysts (M = V, Cr, Mn, Fe, Co, Ni, Cu, Mo, and W) containing small amount of M (M/Si = 1/13200). Formaldehyde space-time yield reached 870 g kg(cat)(-1) h(-1) over the Cu/SBA-15 under the conditions maintaining single-pass formaldehyde yield higher than 1%. The turnover frequency for HCHO formation was 5.6 s(-1) under the same conditions, significantly higher than other catalysts reported so far.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/62903]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	LI, Y,CHEN, SL,ZHANG, QH,et al. Copper-catalyzed selective oxidation of methane to formaldehyde by oxygen[J]. http://dx.doi.org/10.1246/cl.2006.572,2006.
APA	LI, Y,CHEN, SL,ZHANG, QH,WANG, Y,&王野.(2006).Copper-catalyzed selective oxidation of methane to formaldehyde by oxygen.http://dx.doi.org/10.1246/cl.2006.572.
MLA	LI, Y,et al."Copper-catalyzed selective oxidation of methane to formaldehyde by oxygen".http://dx.doi.org/10.1246/cl.2006.572 (2006).