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	Preparation and characterization of high performance Sm05Sr05CoO3 cathodes
	Wang,SZ ; Liu,X ; Wang SZ(王世忠)
	2004-04
关键词	OXIDE FUEL-CELLS ELECTROCHEMICAL PERFORMANCE COMPOSITE CATHODES ION CONDUCTOR ELECTRODES OXYGEN MECHANISM
英文摘要	Sm0. 5Sr0.5CoO3(SSC) powders were prepared using solid-state reaction. The XRD pattern of SSC corresponded to a desired perovskite structure. SSC electrodes sintered at various temperatures (1173 similar to 1373 K) and SSC-La0. 8Sr0. 2Ga0. 8Mg0.15Co0.05O3 (SSC-LSGMC5), SSC-Lao(0.8)Sr(0.2)Ga(0.8)Mg(0.08)Co(0.11)O(3) (SSC-LSGMC11) composite cathodes sintered at 1173 K were studied using SEM, impedance spectroscopy, and DC (direct current) polarization. The electrodes studied were prepared on La0.9Sr0.1Ga0.8Mg0.2O3 electrolytes using screen-printing. The particle size of SSC electrodes increased with sintering temperatures, and the porosity decreased accordingly. The addition of LSGMC5 and LSGMC11 into SSC had no obvious effect on the microstructure of SSC electrodes. The results of AC (alternative current) impedance spectroscopy and DC polarization showed that the activity of SSC electrodes increased with decreasing sintering temperature, and the optimum sintering temperature for SSC electrodes was about 1173 K. The addition of LSGMC5 or LSGMC11 into SSC improved both the activity and stability of SSC electrodes significantly.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/62745]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Wang,SZ,Liu,X,Wang SZ. Preparation and characterization of high performance Sm05Sr05CoO3 cathodes[J],2004.
APA	Wang,SZ,Liu,X,&王世忠.(2004).Preparation and characterization of high performance Sm05Sr05CoO3 cathodes..
MLA	Wang,SZ,et al."Preparation and characterization of high performance Sm05Sr05CoO3 cathodes".(2004).

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