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	Synthesis and photophysical properties of trimetallic acetylide complexes with a 1,3,5-triazine core
	Hu, Q. Y. ; Lu, W. X. ; Tang, H. D. ; Sung, H. H. Y. ; Wen, T. B. ; Williams, I. D. ; Wong, G. K. L. ; Lin, Z. Y. ; Jia, G. C. ; Wen TB(温庭斌)
	2005
关键词	NONLINEAR-OPTICAL-PROPERTIES HYPER-RAYLEIGH SCATTERING RUTHENIUM(II) SIGMA-ACETYLIDE TRANSITION-METAL-COMPLEXES STAR-SHAPED COMPOUNDS ORGANOMETALLIC COMPLEXES 2-PHOTON ABSORPTION 2,4,6-TRIPHENYL-1,3,5-TRIAZINE UNIT 1ST HYPERPOLARIZABILITIES PALLADIUM(II) COMPLEXES
英文摘要	Treatment of 2,4,6-tris(4-bromophenyl)-1,3,5-triazine (2,4,6-(4-BrC6H4)(3)-1,3,5-C3N3) with HC&3bond; CSiMe3 in the presence of Pd(PPh3)(4)/CuI and NEt3 produces 2,4,6-[4-(Me3SiC&3bond; C)C6H4](3)-1,3,5-C3N3, which reacts with Bu4NF to yield 2,4,6-[4-(HC&3bond; C)C6H4](3)-1,3,5-C3N3. Reaction of 2,4,6-[4-(HC&3bond; C)C6H4](3)-1,3,5-C3N3 with AuCl(PPh3) in the presence of NEt3 produces the gold acetylide complex 2,4,6-[4-((PPh3)AuC&3bond; C)C6H4](3)-1,3,5-C3N3. Treatment of 2,4,6-[4-(HC&3bond; C)C6H4](3)-1,3,5-C3N3 with cis-RuCl2(dppe)(2)/NaPF6 followed by NEt3 gives 2,4,6-[4-(Cl(dppe)(2)RuC&3bond; C)C6H4](3)-1,3,5-C3N3, which reacts with p-HC&3bond; CC6H4R (R = OCH3, NO2) to give 2,4,6-[4-((4-RC6H4C&3bond; C)(dppe)(2)RuC&3bond; C)C6H4](3)-1,3,5-C3N3. The electrochemical and photo-physical properties of the new complexes have been investigated.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/62711]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Hu, Q. Y.,Lu, W. X.,Tang, H. D.,et al. Synthesis and photophysical properties of trimetallic acetylide complexes with a 1,3,5-triazine core[J],2005.
APA	Hu, Q. Y..,Lu, W. X..,Tang, H. D..,Sung, H. H. Y..,Wen, T. B..,...&温庭斌.(2005).Synthesis and photophysical properties of trimetallic acetylide complexes with a 1,3,5-triazine core..
MLA	Hu, Q. Y.,et al."Synthesis and photophysical properties of trimetallic acetylide complexes with a 1,3,5-triazine core".(2005).

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