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	Penta-coordinate phosphorous compounds and biochemistry
	Lin, CX ; Lin ZX(林长学) ; Li, YM ; Li YM(李艳梅) ; Cheng, CM ; Cheng CM(成昌梅) ; Han, B ; Han B(韩波) ; Wan, R ; Wan R(万荣) ; Feng, YB ; Feng YB(冯亚兵) ; Zhao, YF ; Zhao YF(赵玉芬)
	2002
关键词	penta-coordinate phosphorus compounds biochemistry nucleotide amino acid origin of life
英文摘要	The relationship between penta-coordinate phosphorus compounds and biochemistry is briefly reviewed. Some interesting phenomena such as peptide formation, ester formation, ester exchange on phosphorus and N to O migration occur at room temperature when the amino group of amino acid is associated with phosphoryl group. Serine or threonine in conjugate of nucleoside-amino acid could recognize different nucleobases. N-phosphoryl Histine and Ser-His dipeptide could cleavage nucleic acid, protein and ester in neutral medium. It is found that the above phenomena all undergo penta-coordinate intermediate of phosphorus atom, which is proposed as the key factor to determine their activities.
语种	中文
出版者	SCIENCE CHINA PRESS
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/12353]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Lin, CX,Lin ZX,Li, YM,et al. Penta-coordinate phosphorous compounds and biochemistry[J],2002.
APA	Lin, CX.,林长学.,Li, YM.,李艳梅.,Cheng, CM.,...&赵玉芬.(2002).Penta-coordinate phosphorous compounds and biochemistry..
MLA	Lin, CX,et al."Penta-coordinate phosphorous compounds and biochemistry".(2002).

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