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Additive effects of alkaline-earth metals and nickel on the performance of Co/gamma-Al(2)O(3) in methane catalytic partial oxidation
Yu, Changlin( Jiangxi Univ Sci & Technol, Sch Mat & Chem Engn) ; Weng, Weizheng ; Weng WZ(翁维正) ; Shu, Qing( Jiangxi Univ Sci & Technol, Sch Mat & Chem Engn) ; Meng, Xiangjie( Jiangxi Univ Sci & Technol, Sch Mat & Chem Engn) ; Zhang, Bin( Jiangxi Univ Sci & Technol, Sch Mat & Chem Engn) ; Chen, Xirong( Jiangxi Univ Sci & Technol, Sch Mat & Chem Engn) ; Zhou, Xiaochun( Jiangxi Univ Sci & Technol, Sch Mat & Chem Engn)
2011-03-31
关键词alkaline-earth metal cobalt-based catalyst gamma-alumina catalytic partial oxidation methane
英文摘要Nano-sized gamma-alumina (gamma-Al(2)O(3)) was first prepared by a precipitation method. Then, active component of cobalt and a series of alkaline-earth metal promoters or nickel (Ni) with different contents were loaded on the gamma-Al(2)O(3) support. The catalysts were characterized by N(2) adsorption-desorption, X-ray diffraction (XRD) and thermogravimetry analysis (TGA). The activity and selectivity of the catalysts in catalytic partial oxidation (CPO) of methane have been compared with Co/-gamma-Al(2)O(3), and it is found that the catalytic activity, selectivity, and stability an; enhanced by the addition of alkaline-earth metals and nickel. The optimal loadings of strontium (Sr) and Ni were 6 and 4 wt%, respectively. This finding will be helpful in designing the trimetallic Co-Ni-Sr/-gamma-Al(2)O(3) catalysts with high performance in CPO of methane.
语种英语
出版者ELSEVIER SCIENCE BV
内容类型期刊论文
源URL[http://dx.doi.org/doi:10.1016/S1003-9953(10)60175-2]  
专题化学化工-已发表论文
推荐引用方式
GB/T 7714
Yu, Changlin,Weng, Weizheng,Weng WZ,et al. Additive effects of alkaline-earth metals and nickel on the performance of Co/gamma-Al(2)O(3) in methane catalytic partial oxidation[J],2011.
APA Yu, Changlin.,Weng, Weizheng.,翁维正.,Shu, Qing.,Meng, Xiangjie.,...&Zhou, Xiaochun.(2011).Additive effects of alkaline-earth metals and nickel on the performance of Co/gamma-Al(2)O(3) in methane catalytic partial oxidation..
MLA Yu, Changlin,et al."Additive effects of alkaline-earth metals and nickel on the performance of Co/gamma-Al(2)O(3) in methane catalytic partial oxidation".(2011).
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