Additive effects of alkaline-earth metals and nickel on the performance of Co/gamma-Al(2)O(3) in methane catalytic partial oxidation | |
Yu, Changlin( Jiangxi Univ Sci & Technol, Sch Mat & Chem Engn) ; Weng, Weizheng ; Weng WZ(翁维正) ; Shu, Qing( Jiangxi Univ Sci & Technol, Sch Mat & Chem Engn) ; Meng, Xiangjie( Jiangxi Univ Sci & Technol, Sch Mat & Chem Engn) ; Zhang, Bin( Jiangxi Univ Sci & Technol, Sch Mat & Chem Engn) ; Chen, Xirong( Jiangxi Univ Sci & Technol, Sch Mat & Chem Engn) ; Zhou, Xiaochun( Jiangxi Univ Sci & Technol, Sch Mat & Chem Engn) | |
2011-03-31 | |
关键词 | alkaline-earth metal cobalt-based catalyst gamma-alumina catalytic partial oxidation methane |
英文摘要 | Nano-sized gamma-alumina (gamma-Al(2)O(3)) was first prepared by a precipitation method. Then, active component of cobalt and a series of alkaline-earth metal promoters or nickel (Ni) with different contents were loaded on the gamma-Al(2)O(3) support. The catalysts were characterized by N(2) adsorption-desorption, X-ray diffraction (XRD) and thermogravimetry analysis (TGA). The activity and selectivity of the catalysts in catalytic partial oxidation (CPO) of methane have been compared with Co/-gamma-Al(2)O(3), and it is found that the catalytic activity, selectivity, and stability an; enhanced by the addition of alkaline-earth metals and nickel. The optimal loadings of strontium (Sr) and Ni were 6 and 4 wt%, respectively. This finding will be helpful in designing the trimetallic Co-Ni-Sr/-gamma-Al(2)O(3) catalysts with high performance in CPO of methane. |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE BV |
内容类型 | 期刊论文 |
源URL | [http://dx.doi.org/doi:10.1016/S1003-9953(10)60175-2] |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Yu, Changlin,Weng, Weizheng,Weng WZ,et al. Additive effects of alkaline-earth metals and nickel on the performance of Co/gamma-Al(2)O(3) in methane catalytic partial oxidation[J],2011. |
APA | Yu, Changlin.,Weng, Weizheng.,翁维正.,Shu, Qing.,Meng, Xiangjie.,...&Zhou, Xiaochun.(2011).Additive effects of alkaline-earth metals and nickel on the performance of Co/gamma-Al(2)O(3) in methane catalytic partial oxidation.. |
MLA | Yu, Changlin,et al."Additive effects of alkaline-earth metals and nickel on the performance of Co/gamma-Al(2)O(3) in methane catalytic partial oxidation".(2011). |
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