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	Diamine substitution reactions of tetrahydrate succinato nickel, cobalt, and zinc coordination polymers
	Zhao-Hui Zhou ; Zhou CH(周朝晖) ; Jin-Mei Yang ; Hui-Lin Wan ; Wan HL(万惠霖)
	2005-06
英文摘要	Investigation on the substitution reactions of tetrahydrate succinato metal coordination polymers with diamine ligands results in the isolations of four new coordination polymers, [M(suc)(bpy)(H2O)(2)](n).nH(2)O (M = Ni, 2; M = Co, 2a), [Ni(suc)(phen)(H2O)](n) (3), and [Zn(suc)(bpy)](n).2nH(2)O (4) (H(2)suc = succinic acid, bpy = 2,2'-bipyridine, and phen = 1,10-phenanthroline). In the isomorphous compounds of 2 and 2a, the metal(II) ions are linked by a bridging succinate ligand to form 1D helix chains in bis-monodentate mode. In compounds 3 and 4, the succinate ligand connects adjacent nickel/zinc(II) atoms through three oxygen atoms from two carboxyl groups, forming an infinite zipper like chain along the a axis. The nickel compound 3 forms a double helix chain through strong hydrogen bonding. Notably, the double-stranded ribbons in compound 4 formed through moderately strong face-to-face pi-pi stacking segregated an unprecedented water chain constructed from dimeric water molecules.
语种	英语
出版者	AMER CHEMICAL SOC
内容类型	期刊论文
源URL	[http://dx.doi.org/doi:10.1021/cg050150r]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Zhao-Hui Zhou,Zhou CH,Jin-Mei Yang,et al. Diamine substitution reactions of tetrahydrate succinato nickel, cobalt, and zinc coordination polymers[J],2005.
APA	Zhao-Hui Zhou,周朝晖,Jin-Mei Yang,Hui-Lin Wan,&万惠霖.(2005).Diamine substitution reactions of tetrahydrate succinato nickel, cobalt, and zinc coordination polymers..
MLA	Zhao-Hui Zhou,et al."Diamine substitution reactions of tetrahydrate succinato nickel, cobalt, and zinc coordination polymers".(2005).

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