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p-dimethylaminobenzaldehyde thiosemicarbazone: A simple novel selective and sensitive fluorescent sensor for mercury(II)
Yu, Yun ; Lin, Li-Rong ; Lin LR(林丽榕) ; Yang, Kai-Bin ; Zhong, Xing ; Huang, Rong-Bin ; Huang RB(黄荣彬) ; Zheng, Lan-Sun ; Zheng LS(郑兰荪)
2005-10
关键词sensor Mercury(II) fluorescence thiosemicarbazone
英文摘要A novel and simple fluorophore, p-dimethylan-tinobenzaidehyde thiosemicarbazone (DMABTS), was prepared in order to find available fluorescent chemosensor for mercuric ion in aquesous solution. DMABTS emitted fluorescence at 448 nm in aqueous solution and its fluorescence intensity was completely quenched upon interaction with Hg" ions, which should be attributed to the 1: 1 complex formation between DMABTS and Hg 2+. The binding constant of the complex was determined as 7.48 x 10(6) Mol l(-1). The linear range of quantitative detection of 0 to 5.77 x 10(-6) Mol l(-1) and the detection limit of 7.7 x 10(-7) Mol l(-1) for Hg2+ in the 6.3 x 10(-6) Mol l(-1) DMABTS aqueous solution were obtained from a calibration curve. The coexistence of several transition metal ions and anions did interfere the fluorometric titration of Hg" ion by less than 4% in the emission change. (c) 2005 Elsevier B.V All rights reserved.
语种英语
出版者ELSEVIER SCIENCE BV
内容类型期刊论文
源URL[http://dx.doi.org/doi:10.1016/j.talanta.2005.09.015]  
专题化学化工-已发表论文
推荐引用方式
GB/T 7714
Yu, Yun,Lin, Li-Rong,Lin LR,et al. p-dimethylaminobenzaldehyde thiosemicarbazone: A simple novel selective and sensitive fluorescent sensor for mercury(II)[J],2005.
APA Yu, Yun.,Lin, Li-Rong.,林丽榕.,Yang, Kai-Bin.,Zhong, Xing.,...&郑兰荪.(2005).p-dimethylaminobenzaldehyde thiosemicarbazone: A simple novel selective and sensitive fluorescent sensor for mercury(II)..
MLA Yu, Yun,et al."p-dimethylaminobenzaldehyde thiosemicarbazone: A simple novel selective and sensitive fluorescent sensor for mercury(II)".(2005).
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