Low-Temperature, Highly Selective, Gas-Phase Oxidation of Benzyl Alcohol over Mesoporous K-Cu-TiO2 with Stable Copper(I) Oxidation State | |
Fan, Jie (浙江大学化学系) ; Dai, Yihu (浙江大学化学系) ; Li, Yunlong (浙江大学化学系) ; Zheng, Nanfeng ; Zheng NF(郑南峰) ; Guo, Junfang ( 浙江大学化学系) ; Yan, Xiaoqing ( 浙江大学化学系) ; Stucky, Galen D. ( Univ Calif Santa Barbara, Dept Chem & Biochem) | |
2009-11-04 | |
关键词 | SOLVENT-FREE OXIDATION MOLECULAR-OXYGEN CATALYSTS GOLD ALDEHYDES GREEN |
英文摘要 | 通讯作者地址: Fan, J (通讯作者), Zhejiang Univ, Dept Chem, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310027, Zhejiang Peoples R China 地址: 1. Zhejiang Univ, Dept Chem, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310027, Zhejiang Peoples R China 2. Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA 电子邮件地址: jfan@zju.edu.cn, stucky@chem.ucsb.edu; A newly developed mesoporous mixed metal oxide (K-Cu-TiO2) catalyst is capable of highly selective, gas-phase benzyl alcoholbenzaldehyde transformation at excellent yields (>99%) under surprisingly low temperatures (203 degrees C, bp of benzyl alcohol). The tow-temperature reaction conditions and integration of K and Cu(I) components into the TiO2 matrix are of vital importance for the stabilization of an active Cu(I) oxidation state and resultant stable, excellent catalytic performance.; National Science Foundations of China 20873122 J0830413 National Science Foundation DMR 02-33728 |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/3184] |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Fan, Jie ,Dai, Yihu ,Li, Yunlong ,et al. Low-Temperature, Highly Selective, Gas-Phase Oxidation of Benzyl Alcohol over Mesoporous K-Cu-TiO2 with Stable Copper(I) Oxidation State[J],2009. |
APA | Fan, Jie .,Dai, Yihu .,Li, Yunlong .,Zheng, Nanfeng.,郑南峰.,...&Stucky, Galen D. .(2009).Low-Temperature, Highly Selective, Gas-Phase Oxidation of Benzyl Alcohol over Mesoporous K-Cu-TiO2 with Stable Copper(I) Oxidation State.. |
MLA | Fan, Jie ,et al."Low-Temperature, Highly Selective, Gas-Phase Oxidation of Benzyl Alcohol over Mesoporous K-Cu-TiO2 with Stable Copper(I) Oxidation State".(2009). |
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