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	Intramolecular hydrogen bonding and anion binding of N-benzamido-N '-benzoylthioureas
	Liu, Wen-Xia ; Jiang, Yun-Bao ; Jiang YB(江云宝)
	2007-12
英文摘要	[GRAPHICS] N-(p-Dimethylamino)benzoyl-N'-phenylthiourea as an N-acylthiourea is known to be unable to bind anions due to a strong intramolecular hydrogen bond (IHB). We show here that by inserting an amido group in the N'-phenyl side the newly designed N-benzamido-N'-benzoylthioureas, despite this IHB too, bind strongly to anions with binding constants on the order of 10(6)-10(7) mol(-1) L. Results suggest that potential anion receptors or organocatalysts could be developed on the basis of this framework with a wide structural diversity.
语种	英语
出版者	AMER CHEMICAL SOC
内容类型	期刊论文
源URL	[http://dx.doi.org/doi:10.1021/jo702159r]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Liu, Wen-Xia,Jiang, Yun-Bao,Jiang YB. Intramolecular hydrogen bonding and anion binding of N-benzamido-N '-benzoylthioureas[J],2007.
APA	Liu, Wen-Xia,Jiang, Yun-Bao,&江云宝.(2007).Intramolecular hydrogen bonding and anion binding of N-benzamido-N '-benzoylthioureas..
MLA	Liu, Wen-Xia,et al."Intramolecular hydrogen bonding and anion binding of N-benzamido-N '-benzoylthioureas".(2007).

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