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Ce(SO4)(2)-mediated Oxidative Coupling of Primary Aromatic Amines in Water
Lu Wen-chao ; Xi Chan-juan
2010-10-12 ; 2010-10-12
关键词Primary aromatic amine Oxidative coupling Cerium sulfate CERIUM(IV) AMMONIUM-NITRATE AZO-COMPOUNDS ANILINES OXIDANT N,N-DIALKYLARYLAMINES Chemistry, Multidisciplinary
中文摘要The oxidative coupling of primary aromatic amines was investigated. Ce(SO4)(2) can mediate the oxidative coupling of primary aromatic amines in water to dimers, trimers and/or tetramers, which depended on the substituents of primary aromatic amines. When 2,6-dimethylaniline or 2,6-diethylaniline was used as substrate, dimer, and tetramer were formed as major products. When 2,6-diisopropylaniline or 2,6-dihaloanilines was used as substrate, dimer, and trimer were formed. The mechanistic aspect was also investigated.
语种英语 ; 英语
出版者HIGHER EDUCATION PRESS ; BEIJING ; SHATANHOU ST 55, BEIJING 100009, PEOPLES R CHINA
内容类型期刊论文
源URL[http://hdl.handle.net/123456789/80815]  
专题清华大学
推荐引用方式
GB/T 7714
Lu Wen-chao,Xi Chan-juan. Ce(SO4)(2)-mediated Oxidative Coupling of Primary Aromatic Amines in Water[J],2010, 2010.
APA Lu Wen-chao,&Xi Chan-juan.(2010).Ce(SO4)(2)-mediated Oxidative Coupling of Primary Aromatic Amines in Water..
MLA Lu Wen-chao,et al."Ce(SO4)(2)-mediated Oxidative Coupling of Primary Aromatic Amines in Water".(2010).
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