QQ客服 官方微博 反馈留言

	Prediction of solubilities of salts, osmotic coefficients and vapor-liquid equilibria for single and mixed solvent electrolyte systems using the LIQUAC model
	Huang, Junqi ; Li, Jiding ; Gmehling, Juergen
	2010-10-12 ; 2010-10-12
关键词	Electrolyte solution Salt solubility LIQUAC VLE Osmotic coefficient EXTENDED UNIQUAC MODEL SOLID EQUILIBRIA TERNARY-SYSTEMS G(E) MODEL THERMODYNAMIC PROPERTIES PHASE-EQUILIBRIA SODIUM-CHLORIDE WATER POTASSIUM NONELECTROLYTES Thermodynamics Chemistry, Physical Engineering, Chemical
中文摘要	The electrolyte model LIQUAC has been used up till now to predict osmotic coefficients, mean ion activity coefficients, the vapor-liquid equilibrium (VLE) behavior, the solubility of gases in single and mixed solvent electrolyte systems, and solubilities of salts in aqueous solutions. In this paper, the required expressions for the calculation of salt solubilities not only in aqueous systems, but also in organic solvents and water-solvent electrolyte systems were deduced in detail based on the LIQUAC model with a fixed reference state and thermodynamic relations. Four salts (NaCl, KCl, NH4Cl and NaF) and two solvent (water and methanol) were selected to test the derived expressions. The results show that the LIQUAC model with a fixed reference state can be used to predict osmotic coefficients, solubilities of salts in aqueous solutions, vapor-liquid equilibria, and the solubilities of salts in water-organic solvent systems with strong electrolytes. (C) 2008 Elsevier B.V. All rights reserved.
语种	英语 ; 英语
出版者	ELSEVIER SCIENCE BV ; AMSTERDAM ; PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
内容类型	期刊论文
源URL	[http://hdl.handle.net/123456789/79514]
专题	清华大学
推荐引用方式 GB/T 7714	Huang, Junqi,Li, Jiding,Gmehling, Juergen. Prediction of solubilities of salts, osmotic coefficients and vapor-liquid equilibria for single and mixed solvent electrolyte systems using the LIQUAC model[J],2010, 2010.
APA	Huang, Junqi,Li, Jiding,&Gmehling, Juergen.(2010).Prediction of solubilities of salts, osmotic coefficients and vapor-liquid equilibria for single and mixed solvent electrolyte systems using the LIQUAC model..
MLA	Huang, Junqi,et al."Prediction of solubilities of salts, osmotic coefficients and vapor-liquid equilibria for single and mixed solvent electrolyte systems using the LIQUAC model".(2010).

个性服务

查看访问统计

相关权益政策

暂无数据

收藏/分享

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。