Hydrogen bonded layer-by-layer assembly of poly(2-vinylpyridine) and poly(acrylic acid): Influence of molecular weight on the formation of microporous film by post-base treatment | |
Zhang, Hongyu ; Wang, Dong ; Wang, Zhiqiang ; Zhang, Xi | |
2010-05-06 ; 2010-05-06 | |
关键词 | layer-by-layer hydrogen bonding microporous films poly(2-vinylpyridine) poly(acrylic acid) ALTERNATING MULTILAYER FILM POLYELECTROLYTE MULTILAYERS THIN-FILMS ULTRATHIN MULTILAYER POLY(4-VINYLPYRIDINE) FABRICATION NANOPARTICLES ADSORPTION DEPOSITION MORPHOLOGY Polymer Science |
中文摘要 | This article describes the buildup of hydrogen bonded multilayer film of poly(2-vinylpyridine) (P2VP) and poly(acrylic acid) (PAA), and the influence of polymer molecular weight on the formation of microporous film by post-base treatment. The formation of a microporous film involved a two-step mechanism: the release of PAA from P2VP/PAA multilayer, and the reorganization of the remaining P2VP on the substrate. Fourier transform infrared spectroscopy (FT-IR) indicated that the release of PAA from hydrogen bonded multilayer was a rapid process, which was almost independent of the molecular weight of PAA. Furthermore, the molecular weight of P2VP had a great effect on micropore formation by immersing the P2VP/PAA multilayer in basic solution. The rate of micropore formation increased with increasing molecular weight. We anticipate that a comparative stud), on P2VP/PAA films containing high or low molecular weight polymer provides a way to control the surface morphology, and will be helpful and constructive for the forthcoming discussion about the formation of the microporous film. (c) 2007 Elsevier Ltd. All rights reserved. |
语种 | 英语 ; 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD ; OXFORD ; THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND |
内容类型 | 期刊论文 |
源URL | [http://hdl.handle.net/123456789/12674] ![]() |
专题 | 清华大学 |
推荐引用方式 GB/T 7714 | Zhang, Hongyu,Wang, Dong,Wang, Zhiqiang,et al. Hydrogen bonded layer-by-layer assembly of poly(2-vinylpyridine) and poly(acrylic acid): Influence of molecular weight on the formation of microporous film by post-base treatment[J],2010, 2010. |
APA | Zhang, Hongyu,Wang, Dong,Wang, Zhiqiang,&Zhang, Xi.(2010).Hydrogen bonded layer-by-layer assembly of poly(2-vinylpyridine) and poly(acrylic acid): Influence of molecular weight on the formation of microporous film by post-base treatment.. |
MLA | Zhang, Hongyu,et al."Hydrogen bonded layer-by-layer assembly of poly(2-vinylpyridine) and poly(acrylic acid): Influence of molecular weight on the formation of microporous film by post-base treatment".(2010). |
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