Electrocatalytic Oxidant-Free Dehydrogenative C-H/S-H Cross-Coupling

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	Electrocatalytic Oxidant-Free Dehydrogenative C-H/S-H Cross-Coupling
	Wang, Pan 1; Tang, Shan 1; Huang, Pengfei 1; Lei AW(雷爱文)1,2
刊名	Angewandte Chemie International Edition
	2017
卷号	56 期号:11 页码:3009-3013
关键词	C-H functionalization C-S bond formation dehydrogenation electrochemistry radical cations
ISSN号	1433-7851
通讯作者	雷爱文
英文摘要	An environmentally friendly electrocatalytic protocol has been developed for dehydrogenative C-H/S-H crosscoupling. This method enabled C-S bond formation under catalyst-and oxidant-free conditions. Under undivided electrolysis conditions, various aryl/heteroaryl thiols and electronrich arenes afforded the C-S bond-formation products in 24-99% yield. A preliminary mechanistic study indicated that the generation of aryl radical cation intermediates is key to the success of this transformation.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the National Natural Science Foundation of China (21390402;21520102003);the Ministry of Science and Technology of China (2012YQ120060);the Fundamental Research Funds for the Central Universities;the Program of Introducing Talents of Discipline to Universities of China (111 Program)
语种	英语
WOS记录号	WOS:000397307600033
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/21644]
专题	兰州化学物理研究所_OSSO国家重点实验室
作者单位	1.Wuhan Univ, Inst Adv Studies, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Wang, Pan,Tang, Shan,Huang, Pengfei,et al. Electrocatalytic Oxidant-Free Dehydrogenative C-H/S-H Cross-Coupling[J]. Angewandte Chemie International Edition,2017,56(11):3009-3013.
APA	Wang, Pan,Tang, Shan,Huang, Pengfei,&Lei AW.(2017).Electrocatalytic Oxidant-Free Dehydrogenative C-H/S-H Cross-Coupling.Angewandte Chemie International Edition,56(11),3009-3013.
MLA	Wang, Pan,et al."Electrocatalytic Oxidant-Free Dehydrogenative C-H/S-H Cross-Coupling".Angewandte Chemie International Edition 56.11(2017):3009-3013.