Rhodium-Complex-Catalyzed Hydroformylation of Olefins with CO2 and Hydrosilane | |
Ren XY(任新意)1,2; Zheng, Zhiyao2; Zhang, Lei2; Wang, Zheng2; Xia CG(夏春谷)1; Ding KL(丁奎岭)2,3 | |
刊名 | Angewandte Chemie International Edition |
2017 | |
卷号 | 56期号:1页码:310-313 |
关键词 | aldehydes carbondi oxide hydroformylation olefins rhodium |
ISSN号 | 1433-7851 |
通讯作者 | 夏春谷 ; 丁奎岭 |
英文摘要 | A rhodium-catalyzed one-pot hydroformylation of olefins with CO2 , hydrosilane, and H2 has been developed that affords the aldehydes in good chemoselectivities at low catalyst loading. Mechanistic studies indicate that the transformation is likely to proceed through a tandem sequence of poly(methylhydrosiloxane) (PMHS) mediated CO2 reduction to CO and a conventional rhodium-catalyzed hydroformylation with CO/H2. The hydrosilylane-mediated reduction of CO2 in preference to aldehydes was found to be crucial for the selective formation of aldehydes under the reaction conditions. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | MOST (2016YFA0202900);the National Natural Science Foundation of China (21421091;21572254);the Chinese Academy of Sciences;the Science and Technology Commission of Shanghai Municipality |
语种 | 英语 |
WOS记录号 | WOS:000394861200047 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/21543] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, 18 Tianshui Middle Rd, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Ren XY,Zheng, Zhiyao,Zhang, Lei,et al. Rhodium-Complex-Catalyzed Hydroformylation of Olefins with CO2 and Hydrosilane[J]. Angewandte Chemie International Edition,2017,56(1):310-313. |
APA | Ren XY,Zheng, Zhiyao,Zhang, Lei,Wang, Zheng,Xia CG,&Ding KL.(2017).Rhodium-Complex-Catalyzed Hydroformylation of Olefins with CO2 and Hydrosilane.Angewandte Chemie International Edition,56(1),310-313. |
MLA | Ren XY,et al."Rhodium-Complex-Catalyzed Hydroformylation of Olefins with CO2 and Hydrosilane".Angewandte Chemie International Edition 56.1(2017):310-313. |
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