Room-temperature processible TiO2 electron selective layers with controllable crystallinity for high efficiency perovskite photovoltaics
Huang, Aibin1,2; Zhu, Jingting1,2; Zheng, Jianyun3; Yu, Yu1,2; Liu, Yan1; Yang, Songwang4; Bao, Shanhu1; Lei, Lei1; Jin, Ping1,5
刊名SOLAR ENERGY MATERIALS AND SOLAR CELLS
2017-04-01
卷号163页码:15-22
关键词Magnetron sputtering TiO2 electron transport layer Crystallinity engineering Perovskite solar cells
英文摘要As a remarkable wide band-gap n-type semiconductor, TiO2 has been widely used as electron selective layer in photovoltaic devices, In this work, TiO2 films with different crystallinity were deposited on FTO glass by DC magnetron sputtering at room temperature. The crystallinity of these films were controlled by precisely adjusting the sputtering power and work pressure. Taking advantages of high visible light transmittance, reduced transport resistance and effective TiO2/perovskite interface with fast electron extraction and carrier separation, high efficiency perovskite solar cells (PSCs) were assembled. The optimum crystallinity of TiO2 compact layer for PSC was defined as 26.3%. Short-circuit current density and fill factor were notably enhanced and power conversion efficiency of the device was improved to 15.76% compared with PSCs based on amorphous (13.3%) and fully crystallized TiO2 (12.9%). This research shaded light on the choice of inorganic carrier transport layers in photovoltaic devices.
WOS标题词Science & Technology ; Technology ; Physical Sciences
类目[WOS]Energy & Fuels ; Materials Science, Multidisciplinary ; Physics, Applied
研究领域[WOS]Energy & Fuels ; Materials Science ; Physics
关键词[WOS]SENSITIZED SOLAR-CELLS ; TRANSPORT LAYER ; OXIDE ; FABRICATION ; EXTRACTION ; DEPOSITION ; FILMS
收录类别SCI
语种英语
WOS记录号WOS:000395839400003
内容类型期刊论文
源URL[http://ir.sic.ac.cn/handle/331005/23684]  
专题上海硅酸盐研究所_古陶瓷与工业陶瓷工程研究中心_期刊论文
作者单位1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Dingxi 1295, Shanghai 200050, Peoples R China
2.Univ Chinese Acad Sci, Yuquan 19, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
4.Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Mat Energy Convers, Heshuo 588, Shanghai 201899, Peoples R China
5.Natl Inst Adv Ind Sci & Technol, Nagoya, Aichi 4638560, Japan
推荐引用方式
GB/T 7714
Huang, Aibin,Zhu, Jingting,Zheng, Jianyun,et al. Room-temperature processible TiO2 electron selective layers with controllable crystallinity for high efficiency perovskite photovoltaics[J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS,2017,163:15-22.
APA Huang, Aibin.,Zhu, Jingting.,Zheng, Jianyun.,Yu, Yu.,Liu, Yan.,...&Jin, Ping.(2017).Room-temperature processible TiO2 electron selective layers with controllable crystallinity for high efficiency perovskite photovoltaics.SOLAR ENERGY MATERIALS AND SOLAR CELLS,163,15-22.
MLA Huang, Aibin,et al."Room-temperature processible TiO2 electron selective layers with controllable crystallinity for high efficiency perovskite photovoltaics".SOLAR ENERGY MATERIALS AND SOLAR CELLS 163(2017):15-22.
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