Non-noble bimetallic alloy encased in nitrogen-doped nanotubes as a highly active and durable electrocatalyst for oxygen reduction reaction

CORC > 上海硅酸盐研究所 > 中国科学院上海硅酸盐研究所 > 高性能陶瓷和超微结构国家重点实验室 > 期刊论文

	Non-noble bimetallic alloy encased in nitrogen-doped nanotubes as a highly active and durable electrocatalyst for oxygen reduction reaction
	Zeng, Liming 1,2; Cui, Xiangzhi 1; Chen, Lisong 1; Ye, Ting 1,2; Huang, Weimin 1; Ma, Ruguang 1; Zhang, Xiaohua 1,2; Shi, Jianlin 1
刊名	CARBON
	2017-04-01
卷号	114 页码:347-355
英文摘要	Exploring highly active, cost-effective and durable oxygen reduction reaction (ORR) electrocatalysts as substitutes for the rare platinum -based catalysts is of great significance in energy conversion and storage devices, such as alkaline fuel cells, metal-air batteries, etc. Herein, we fabricated a new type ORR electrocatalyst of Ni-Co nanocrystal alloy encapsulated in N-doped carbon nanotubes (NCNTs) through a facile, scalable route utilizing nickel acetate and cobalt chloride as metallic Ni and Co precursors, thiourea as a nitrogen and carbon source, respectively, under a Ni/Co atomic ratio of 3:7 at 700 degrees C. The obtained nanocomposite catalyst NiCo@NCNT-700 exhibited an outstanding ORR activity close to that of the state-of-the-art Pt/C catalyst and superior operational durability under alkaline conditions, which could be attributed to the co-contributions among the uniformly distributed Ni-Co alloy nanoparticles, graphitic NCNTs and the formation of Co-N species. This work provides a new insight for the rational design and development of efficient non-noble metal electrocatalysts by integrating electrochemically active units into the nanocomposite for challenging electrochemical energy-related technologies. (C) 2016 Elsevier Ltd. All rights reserved.
WOS标题词	Science & Technology ; Physical Sciences ; Technology
类目[WOS]	Chemistry, Physical ; Materials Science, Multidisciplinary
研究领域[WOS]	Chemistry ; Materials Science
关键词[WOS]	HIGH-PERFORMANCE ELECTROCATALYSTS ; CARBON ELECTROCATALYSTS ; GRAPHENE ; EFFICIENT ; COBALT ; CATALYST ; SULFUR ; IRON
收录类别	SCI
语种	英语
WOS记录号	WOS:000393249600039
内容类型	期刊论文
源URL	[http://ir.sic.ac.cn/handle/331005/23476]
专题	上海硅酸盐研究所_高性能陶瓷和超微结构国家重点实验室_期刊论文
作者单位	1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China 2.Chinese Acad Sci, Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zeng, Liming,Cui, Xiangzhi,Chen, Lisong,et al. Non-noble bimetallic alloy encased in nitrogen-doped nanotubes as a highly active and durable electrocatalyst for oxygen reduction reaction[J]. CARBON,2017,114:347-355.
APA	Zeng, Liming.,Cui, Xiangzhi.,Chen, Lisong.,Ye, Ting.,Huang, Weimin.,...&Shi, Jianlin.(2017).Non-noble bimetallic alloy encased in nitrogen-doped nanotubes as a highly active and durable electrocatalyst for oxygen reduction reaction.CARBON,114,347-355.
MLA	Zeng, Liming,et al."Non-noble bimetallic alloy encased in nitrogen-doped nanotubes as a highly active and durable electrocatalyst for oxygen reduction reaction".CARBON 114(2017):347-355.