Catalysts screening, optimization and mechanism studies of dimethylhexane-1,6-dicarbamate synthesis from 1,6-hexanediamine and dimethyl carbonate over Mn(OAc)(2) catalyst | |
Zhao, Liyan1,2; He, Peng1; Wang, Liguo1; Ammar, Muhammad1,2; Cao, Yan1; Li, Huiquan1 | |
刊名 | CATALYSIS TODAY |
2017-03-01 | |
卷号 | 281页码:392-401 |
关键词 | Dimethyl Carbonate (Dmc) Mechanism Dimethylhexane-1 Homogeneous Catalyst 6-dicarbamate (Hdc) |
ISSN号 | 0920-5861 |
DOI | 10.1016/j.cattod.2016.02.059 |
文献子类 | Article |
英文摘要 | The catalytic synthesis of dimethylhexane-1,6-dicarbamate (HDC) from 1,6-hexanediamine (HDA) and dimethyl carbonate (DMC) over a series of homogeneous catalysts (e.g., metallic nitrates and acetates) were investigated. Mn(OAc)(2) was found to be the most effective catalyst for this reaction. Under the optimum reaction conditions (reaction temperature of 363 K, DMC-to-HDA molar ratio of 4:1, catalyst concentration of 7 wt% (based on HDA), and reaction time of 5 h), HDC yield can reach as high as 98.0% with HDA totally converted. Online in-situ Fourier Transform Infrared (FTIR) and Density Functional Theory (DFT) calculations were used together to investigate the interactions between Mn(OAc)(2) and substrates. The results indicated that both of HDA and DMC had interactions with Mn(OAc)(2), but the energy barriers of the transition states (TS) of DMC (DMC-TS) was higher than that of HDA (HDA-TS), which meant that HDA was easier to interact with Mn(OAc)(2) to form new complex than DMC. The whole process can be proposed that, the new species II, which was formed by the interaction of HDA and Mn(OAc)(2), attacked carbonyl carbon of DMC to generate intermediate HMC and finally to HDC. The experimental data and calculation results are in good agreement with each other. (C) 2016 Elsevier B.V. All rights reserved. |
WOS关键词 | Zinc Acetate ; Polyatomic-molecules ; Diethyl Carbonate ; Transition-states ; Alkyl Carbamate ; Methoxycarbonylation ; 1,6-hexamethylenediamine ; Dicarbamate ; Methanol ; Dioxide |
WOS研究方向 | Chemistry ; Engineering |
语种 | 英语 |
WOS记录号 | WOS:000390623300020 |
内容类型 | 期刊论文 |
源URL | [http://ir.ipe.ac.cn/handle/122111/21862] |
专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
作者单位 | 1.Chinese Acad Sci, Key Lab Green Proc & Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Inst Proc Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao, Liyan,He, Peng,Wang, Liguo,et al. Catalysts screening, optimization and mechanism studies of dimethylhexane-1,6-dicarbamate synthesis from 1,6-hexanediamine and dimethyl carbonate over Mn(OAc)(2) catalyst[J]. CATALYSIS TODAY,2017,281:392-401. |
APA | Zhao, Liyan,He, Peng,Wang, Liguo,Ammar, Muhammad,Cao, Yan,&Li, Huiquan.(2017).Catalysts screening, optimization and mechanism studies of dimethylhexane-1,6-dicarbamate synthesis from 1,6-hexanediamine and dimethyl carbonate over Mn(OAc)(2) catalyst.CATALYSIS TODAY,281,392-401. |
MLA | Zhao, Liyan,et al."Catalysts screening, optimization and mechanism studies of dimethylhexane-1,6-dicarbamate synthesis from 1,6-hexanediamine and dimethyl carbonate over Mn(OAc)(2) catalyst".CATALYSIS TODAY 281(2017):392-401. |
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