Production of Phenolic Compounds from Bagasse Lignin via Catalytic Pyrolysis of CaZr1-xFexO3

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	Production of Phenolic Compounds from Bagasse Lignin via Catalytic Pyrolysis of CaZr1-xFexO3
	Chen Yanguang 1,2; Wang Xinhui 1,2; Han Hongjing 1,2; Wang Haiying 1,2; An Hongyu 1,2; Song Hua 1,2; Gong Xuzhong 3; Zhang Jian 1,2
刊名	CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
	2017-02-10
卷号	38 期号:2 页码:252-260
关键词	CaZr1-xFexO3 Bagasse lignin Catalytic pyrolysis Phenolic compound
ISSN号	0251-0790
英文摘要	Chemical conversion is an important approach to obtain chemical products from bagasse lignin (BL) which favors in resource and high. value utilization of lignin. A series of perovskite. type mixed ionic and electronic conductors CaZr1-xFexO3 (CZF-x; x = 0, 0.2, 0.4, 0.8, 1.0) were prepared via the solid state re. action method. The crystal form, morphology, metal valence state and thermal stability were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), X-ray photoelectric spectroscopy (XPS) and thermogravimetric analysis and differential thermal analysis (TG-DTA). Catalytic performance for producing phenolic compounds from bagasse lignin via catalytic pyrolysis was evaluated in a fixed bed micro. reactor. The results show that the CaZr1-xFexO3 pellets after calcinations deposit randomly in the form of irregular grains of flake with compact structure. As the doping amount of Fe increases, the characteristic peaks of mixed ionic and electronic conductor shift to large angle, the cell volume of crystal and the grain size decrease. Moreover, the pyrolysis temperature of BL was significantly reduced under the action of CaZr0.2 Fe0.8O3 (CZFO-0. 2). In the test of fixed bed micro. reactor, the yield of liquid product was 23.71%. The phenolic product was mainly consisting with phenols, guaiacyl groups, catechol and syringyl groups; their selectivities were 35.19%, 6.18%, 10.68% and 14.21% respectively. The rest of liquid products were benzenes and methoxy aromatics. The deactivated catalyst was regenerated by oxidation to removing the coke coated on the surface and exhibited the high structural stability and the better catalytic activity. Due to the enhancement of breakage for aromatic alkyl side chain by CZFO-0.2, the contents of CH4 and CmHn in BL pyrolysis gas increased.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	MILLED WOOD LIGNIN ; ALKALI LIGNIN ; AROMATIC-ALDEHYDES ; OXIDATION
收录类别	SCI
语种	英语
WOS记录号	WOS:000392523900013
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/21879]
专题	过程工程研究所_多相复杂系统国家重点实验室
作者单位	1.Northeast Petr Univ, Coll Chem & Chem Engn, Daqing 163318, Peoples R China 2.Northeast Petr Univ, Prov Key Lab Oil & Gas Chem Technol, Daqing 163318, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Chen Yanguang,Wang Xinhui,Han Hongjing,et al. Production of Phenolic Compounds from Bagasse Lignin via Catalytic Pyrolysis of CaZr1-xFexO3[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2017,38(2):252-260.
APA	Chen Yanguang.,Wang Xinhui.,Han Hongjing.,Wang Haiying.,An Hongyu.,...&Zhang Jian.(2017).Production of Phenolic Compounds from Bagasse Lignin via Catalytic Pyrolysis of CaZr1-xFexO3.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,38(2),252-260.
MLA	Chen Yanguang,et al."Production of Phenolic Compounds from Bagasse Lignin via Catalytic Pyrolysis of CaZr1-xFexO3".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 38.2(2017):252-260.