Pressure-Induced Phase Transition of Hydrogen Storage Material Hydrazine Bisborane: Evolution of Dihydrogen Bonds

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	Pressure-Induced Phase Transition of Hydrogen Storage Material Hydrazine Bisborane: Evolution of Dihydrogen Bonds
	Qi, GY; Wang, K; Yang, K; Zou, B
刊名	JOURNAL OF PHYSICAL CHEMISTRY C
	2016
卷号	120 期号:38 页码:21293-21298
ISSN号	1932-7447
通讯作者	Wang, K ; Zou, B (reprint author), Jilin Univ, State Key Lab Superhard Mat, Changchun 130012, Peoples R China.
英文摘要	We report the high-pressure behavior of dihydrogen-bonded hydrogen storage, material hydrazine bisborane (BH3N2H4BH3, HBB) via in Situ angle-dispersive X-ray diffraction (ADXRD) and Raman spectroscopy in a diamond anvil cell up to 2.0 GPa. A reversible phase transition at 0.4 GPa was confirmed by ADXRD experiments. The Rietveld refinement showed the high-pressure phase was consistent with the crystal structure of alpha'-phase (low-temperature phase). through the analysis of structure changes, Raman spectroscopy, and the Hirshfeld surface, we studied the evolution of dihydrogen bonds under high pressure and attributed the,pressure-induced phase transition to the distortion and rotation of the NH2-NH2 group. This work will further the understanding of the characteristics of dihydrogen bonds and provide some contribution to future hydrogen storage applications of HBB.
收录类别	SCI
语种	英语
WOS记录号	WOS:000384626800018
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/26605]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
推荐引用方式 GB/T 7714	Qi, GY,Wang, K,Yang, K,et al. Pressure-Induced Phase Transition of Hydrogen Storage Material Hydrazine Bisborane: Evolution of Dihydrogen Bonds[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2016,120(38):21293-21298.
APA	Qi, GY,Wang, K,Yang, K,&Zou, B.(2016).Pressure-Induced Phase Transition of Hydrogen Storage Material Hydrazine Bisborane: Evolution of Dihydrogen Bonds.JOURNAL OF PHYSICAL CHEMISTRY C,120(38),21293-21298.
MLA	Qi, GY,et al."Pressure-Induced Phase Transition of Hydrogen Storage Material Hydrazine Bisborane: Evolution of Dihydrogen Bonds".JOURNAL OF PHYSICAL CHEMISTRY C 120.38(2016):21293-21298.